Öz
Bu çalışmada; 2-asetil-benzofuran bromlanarak bromoasetilbenzofuran elde edildi. Primer ve
sekonder aminlerin ditiyokarbamat tuzları ile α-haloketonun reaksiyonu sonucunda oluşan
ürünler incelendi. Elde edilen ditiyokarbamat esterlerinin yapıları 1H-NMR, 13C-NMR ve FTIR
gibi spektroskopik yöntemler kullanılarak karakterize edildi.
Anahtar Kelimeler
Benzofuran α-Haloketon Ditiyokarbamat Tuzu Ditiyokarbamat esterleri
Kaynakça
- T. L. Gilchrist, Heterocyclic Chemistry, Longman Group UK Lim. England, 1985, 174.
- D. Bogdal, M. Warzala, Tetrahedron, 2000, 56, 8769-8773.
- M. W. Khan, M. J. Alam, M. A. Rashid, R. Chowdhury, Bioorganic & Medicinal Chemistry, 2005, 13, 4796-4805.
- C. Kırılmış, M. Ahmedzade, S. Servi, M. Koca, A. Kizirgil, C. Kazaz, European Journal of Medicinal Chemistry, 2008, 43, 300-308.
- C. L. Kao, J. W. Chern, J. Org. Chem., 2002, 67, 6772-6787.
- K. E. Kinnamon, B. T. Poon, W. L. Hanson, V.B. Waits, Experimental Parasitology, 1998, 89, 251-256.
- M. Kulka, Canadian Journal of Chemistry, 1956, 34, 1093-1100.
- L. Drobnica, P. Kristian, J. Augustin, Chichester: John Wiley and Sons., 1977.
- K. Hirai, H. Sugimoto, T. Ishiba,. Reaction of 1,3-Dithiolium Cation with Xanthate and Dithiocarbamate Anions, Journal of Organic Chemistry, 1977, 42 (9), 1543-1549.
Öz
In this study; bromoacetylbenzofuran was obtained by bromizing 2-acetyl-benzofuran. Dithiocarbamatesalts of primary and secondary amines with products of α-haloketon reaction were examined. The structures of derived dithiocarbamate esters were characterized by 1HNMR, 13C-NMR and FT-IR spectroscopic methods.
Anahtar Kelimeler
Benzofuran α-haloketone Dithiocarbamate Salt Dithiocarbamate Esthers
Kaynakça
- T. L. Gilchrist, Heterocyclic Chemistry, Longman Group UK Lim. England, 1985, 174.
- D. Bogdal, M. Warzala, Tetrahedron, 2000, 56, 8769-8773.
- M. W. Khan, M. J. Alam, M. A. Rashid, R. Chowdhury, Bioorganic & Medicinal Chemistry, 2005, 13, 4796-4805.
- C. Kırılmış, M. Ahmedzade, S. Servi, M. Koca, A. Kizirgil, C. Kazaz, European Journal of Medicinal Chemistry, 2008, 43, 300-308.
- C. L. Kao, J. W. Chern, J. Org. Chem., 2002, 67, 6772-6787.
- K. E. Kinnamon, B. T. Poon, W. L. Hanson, V.B. Waits, Experimental Parasitology, 1998, 89, 251-256.
- M. Kulka, Canadian Journal of Chemistry, 1956, 34, 1093-1100.
- L. Drobnica, P. Kristian, J. Augustin, Chichester: John Wiley and Sons., 1977.
- K. Hirai, H. Sugimoto, T. Ishiba,. Reaction of 1,3-Dithiolium Cation with Xanthate and Dithiocarbamate Anions, Journal of Organic Chemistry, 1977, 42 (9), 1543-1549.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Mühendislik |
| Bölüm | Kimya |
| Yazarlar | |
| Yayımlanma Tarihi | 10 Temmuz 2015 |
| Gönderilme Tarihi | 10 Temmuz 2015 |
| Yayımlandığı Sayı | Yıl 2015 Cilt: 5 Sayı: 1 |
Kaynak Göster
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