Investigation of Electrochemical Properties and Behaviors of NBITEP Molecule; Availability of Sensor Electrode in Determination of Hg2+ with SWAdSV Technique
Abstract
This Master's Thesis focuses on the synthesis and structural elucidation of 4-(2-((6-nitro-1h-benzo[d]imidazol-2-yl)thio)ethyl)phenol (NBITEP) molecule, along with its electrochemical behaviors. Electrochemical studies were carried out employing a glassy carbon (GC) electrode as the working electrode. The cyclic voltammetry (CV) technique was utilized for modification and characterization processes. Furthermore, the potential of the modified surface as a sensor electrode for Hg2+ ion detection was investigated using square wave adsorptive stripping voltammetry (SWAdSV). Detailed examinations were conducted in a phosphate buffer solution (PBS) medium specifically for Hg2+ ion detection, demonstrating the suitability of the reduced NBITEP modified GC electrode surface as a sensor electrode.
References
- Hu, J., Shao, D., Chen, C., Sheng, G., Ren, X., & Wang, X. (2011). Removal of 1-naphthylamine from aqueous solution by multiwall carbon nanotubes/iron oxides/cyclodextrin composite. J Hazard Mater, 185(1), 463-471. https://doi.org/10.1016/j.jhazmat.2010.09.055
- Islamoğlu, N., Mülazımoğlu, I. E., & Demir Mülazımoğlu, A. (2023). Sensitive and selective determination of paracetamol in antipyretic children's syrup with a polyglycine modified glassy carbon electrode. Anal Methods, 15(33), 4149-4158. https://doi.org/10.1039/d3ay00789h
- Korkmaz, S., Bosnali, W., Mülazımoğlu, I. E., & Mülazımoğlu, A. D. (2023). Voltammetric Determination of Acrylamide Using Coal Tar Pitch Modified Pencil Graphite Electrode by SWV. Food Analytical Methods, 16(11-12), 1738-1745. https://doi.org/10.1007/s12161-023-02540-2
- Leventis, H. C., Wildgoose, G. G., Davies, I. G., Jiang, L., Jones, T. G. J., & Compton, R. G. (2005). Multiwalled carbon nanotubes covalently modified with Fast Black K. Chemphyschem, 6(4), 590-595. https://doi.org/10.1002/cphc.200400536
- Li, M., Gou, H. L., Al-Ogaidi, I., & Wu, N. Q. (2013). Nanostructured Sensors for Detection of Heavy Metals: A Review. Acs Sustainable Chemistry & Engineering, 1(7), 713-723. https://doi.org/10.1021/sc400019a
- Mülazımoğlu, A. D., & Mülazımoğlu, I. E. (2013). Electrochemical Properties of MDA/GC Electrode and Investigation of Usability as Sensor Electrode for Determination of Que, Kae, Lut and Gal Using CV, DPV and SWV. Food Analytical Methods, 6(1), 141-147. https://doi.org/10.1007/s12161-012-9426-2
- Mülazımoğlu, A. D., Mülazımoğlu, I. E., & Yılmaz, E. (2012). Determination of copper ions based on newly developed poly-chrysin modified glassy carbon sensor electrode. Reviews in Analytical Chemistry, 31(2), 131-137. https://doi.org/10.1515/Revac.2011.151
- Mülazımoğlu, I. E., & Mülazımoğlu, A. D. (2012). Investigation of Sensitivity Against Different Flavonoid Derivatives of Aminophenyl-Modified Glassy Carbon Sensor Electrode and Antioxidant Activities. Food Analytical Methods, 5(6), 1419-1426. https://doi.org/10.1007/s12161-012-9393-7
- Mülazımoğlu, I. E., Mülazımoğlu, A. D., & Yılmaz, E. (2011). Determination of quantitative phenol in tap water samples as electrochemical using 3,3′-diaminobenzidine modified glassy carbon sensor electrode. Desalination, 268(1-3), 227-232. https://doi.org/10.1016/j.desal.2010.10.033
- Pumera, M., Ambrosi, A., Bonanni, A., Chng, E. L. K., & Poh, H. L. (2010). Graphene for electrochemical sensing and biosensing. Trac-Trends in Analytical Chemistry, 29(9), 954-965. https://doi.org/10.1016/j.trac.2010.05.011
- Shao, Y. Y., Wang, J., Wu, H., Liu, J., Aksay, I. A., & Lin, Y. H. (2010). Graphene Based Electrochemical Sensors and Biosensors: A Review. Electroanalysis, 22(10), 1027-1036. https://doi.org/10.1002/elan.200900571
- Yurttaş, L., Özkay, Y., Demirci, F., Göger, G., Yildirim, S. U., Abu Mohsen, U., Öztürk, O., & Kaplancikli, Z. A. (2014). Synthesis, anticandidal activity, and cytotoxicity of some thiazole derivatives with dithiocarbamate side chains. Turkish Journal of Chemistry, 38(5), 815-824. https://doi.org/10.3906/kim-1312-62
- Yurttaş, L., Özkay, Y., Duran, M., Turan-Zitouni, G., Özdemir, A., Cantürk, Z., Küçükoglu, K., & Kaplancikli, Z. A. (2016). Synthesis and antimicrobial activity evaluation of new dithiocarbamate derivatives bearing thiazole/benzothiazole rings. Phosphorus Sulfur and Silicon and the Related Elements, 191(8), 1166-1173. https://doi.org/10.1080/10426507.2016.1150277
- Zheng, D., Li, H. H., Lu, B. Y., Xu, Z. H., & Chen, H. Y. (2008). Electrochemical properties of ferrocene adsorbed on multi-walled carbon nanotubes electrode. Thin Solid Films, 516(8), 2151-2157. https://doi.org/10.1016/j.tsf.2007.09.018
NBITEP Molekülünün Elektrokimyasal Özelliklerinin ve Davranışlarının İncelenmesi; SWAdSV Tekniği ile Hg2+’nın Tayininde Sensör Elektrotun Kullanılabilirliği
Abstract
Bu çalışmada, 4-(2-((6-nitro-1h-benzo[d]imidazol-2-il)tiyo)etil)fenol (NBITEP) molekülü sentezlenmiş, karakterize edilmiş ve çalışma bir Yüksek Lisans Tezi olarak sunulmuştur. Elektrokimyasal incelemelerde camsı karbon (GC) elektrot, çalışma elektrodu olarak kullanılmıştır. Modifikasyon ve karakterizasyon işlemlerinde dönüşümlü voltametri (CV) tekniğinin kullanıldığı çalışmada, modifiye edilmiş yüzeyin Hg2+ iyonu için bir sensör elektrot olarak kullanılabilirliği, kare dalga adsorptif sıyırma voltametri (SWAdSV) tekniği ile araştırılmıştır. Fosfat tampon çözeltisi (PBS) ortamında gerçekleştirilen çalışmalar, Hg2+ iyonu için indirgenmiş NBITEP modifiye GC elektrotun bir sensör elektrot olarak kullanılabileceğini ortaya koymuştur.
Keywords
References
- Hu, J., Shao, D., Chen, C., Sheng, G., Ren, X., & Wang, X. (2011). Removal of 1-naphthylamine from aqueous solution by multiwall carbon nanotubes/iron oxides/cyclodextrin composite. J Hazard Mater, 185(1), 463-471. https://doi.org/10.1016/j.jhazmat.2010.09.055
- Islamoğlu, N., Mülazımoğlu, I. E., & Demir Mülazımoğlu, A. (2023). Sensitive and selective determination of paracetamol in antipyretic children's syrup with a polyglycine modified glassy carbon electrode. Anal Methods, 15(33), 4149-4158. https://doi.org/10.1039/d3ay00789h
- Korkmaz, S., Bosnali, W., Mülazımoğlu, I. E., & Mülazımoğlu, A. D. (2023). Voltammetric Determination of Acrylamide Using Coal Tar Pitch Modified Pencil Graphite Electrode by SWV. Food Analytical Methods, 16(11-12), 1738-1745. https://doi.org/10.1007/s12161-023-02540-2
- Leventis, H. C., Wildgoose, G. G., Davies, I. G., Jiang, L., Jones, T. G. J., & Compton, R. G. (2005). Multiwalled carbon nanotubes covalently modified with Fast Black K. Chemphyschem, 6(4), 590-595. https://doi.org/10.1002/cphc.200400536
- Li, M., Gou, H. L., Al-Ogaidi, I., & Wu, N. Q. (2013). Nanostructured Sensors for Detection of Heavy Metals: A Review. Acs Sustainable Chemistry & Engineering, 1(7), 713-723. https://doi.org/10.1021/sc400019a
- Mülazımoğlu, A. D., & Mülazımoğlu, I. E. (2013). Electrochemical Properties of MDA/GC Electrode and Investigation of Usability as Sensor Electrode for Determination of Que, Kae, Lut and Gal Using CV, DPV and SWV. Food Analytical Methods, 6(1), 141-147. https://doi.org/10.1007/s12161-012-9426-2
- Mülazımoğlu, A. D., Mülazımoğlu, I. E., & Yılmaz, E. (2012). Determination of copper ions based on newly developed poly-chrysin modified glassy carbon sensor electrode. Reviews in Analytical Chemistry, 31(2), 131-137. https://doi.org/10.1515/Revac.2011.151
- Mülazımoğlu, I. E., & Mülazımoğlu, A. D. (2012). Investigation of Sensitivity Against Different Flavonoid Derivatives of Aminophenyl-Modified Glassy Carbon Sensor Electrode and Antioxidant Activities. Food Analytical Methods, 5(6), 1419-1426. https://doi.org/10.1007/s12161-012-9393-7
- Mülazımoğlu, I. E., Mülazımoğlu, A. D., & Yılmaz, E. (2011). Determination of quantitative phenol in tap water samples as electrochemical using 3,3′-diaminobenzidine modified glassy carbon sensor electrode. Desalination, 268(1-3), 227-232. https://doi.org/10.1016/j.desal.2010.10.033
- Pumera, M., Ambrosi, A., Bonanni, A., Chng, E. L. K., & Poh, H. L. (2010). Graphene for electrochemical sensing and biosensing. Trac-Trends in Analytical Chemistry, 29(9), 954-965. https://doi.org/10.1016/j.trac.2010.05.011
- Shao, Y. Y., Wang, J., Wu, H., Liu, J., Aksay, I. A., & Lin, Y. H. (2010). Graphene Based Electrochemical Sensors and Biosensors: A Review. Electroanalysis, 22(10), 1027-1036. https://doi.org/10.1002/elan.200900571
- Yurttaş, L., Özkay, Y., Demirci, F., Göger, G., Yildirim, S. U., Abu Mohsen, U., Öztürk, O., & Kaplancikli, Z. A. (2014). Synthesis, anticandidal activity, and cytotoxicity of some thiazole derivatives with dithiocarbamate side chains. Turkish Journal of Chemistry, 38(5), 815-824. https://doi.org/10.3906/kim-1312-62
- Yurttaş, L., Özkay, Y., Duran, M., Turan-Zitouni, G., Özdemir, A., Cantürk, Z., Küçükoglu, K., & Kaplancikli, Z. A. (2016). Synthesis and antimicrobial activity evaluation of new dithiocarbamate derivatives bearing thiazole/benzothiazole rings. Phosphorus Sulfur and Silicon and the Related Elements, 191(8), 1166-1173. https://doi.org/10.1080/10426507.2016.1150277
- Zheng, D., Li, H. H., Lu, B. Y., Xu, Z. H., & Chen, H. Y. (2008). Electrochemical properties of ferrocene adsorbed on multi-walled carbon nanotubes electrode. Thin Solid Films, 516(8), 2151-2157. https://doi.org/10.1016/j.tsf.2007.09.018
Details
| Primary Language | English |
|---|---|
| Subjects | Electroanalytical Chemistry, Sensor Technology |
| Journal Section | Research Articles |
| Authors | |
| Publication Date | April 24, 2024 |
| Submission Date | March 20, 2024 |
| Acceptance Date | April 2, 2024 |
| Published in Issue | Year 2024 Volume: 50 Issue: 1 |
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Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Metin AKSOY
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.
It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" since 2009.
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