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Epr Spectroscopic Investigation of Mn+2 Acesulfam Metal Complex, [Mn(acs)2(H2O)4]

Year 2020, Volume: 5 Issue: 1, 49 - 54, 18.06.2020
https://doi.org/10.33484/sinopfbd.660660

Abstract

In this study, the structure of Mn+2 doped [Mn(acs)2(H2O)4] acesulfame metal complex was investigated by EPR spectroscopy. Transition metal ion complexes have important applications in both science and technology. Some of these complexes are formed using paramagnetic metal ions Mn+2, VO+2, Cu+2, Fe+3, Cr+3 and therefore are analyzed with EPR spectroscopy to provide structural information. The synthetic sweetener acesulfame is widely used in food and medicine and has widely used in cosmetics. The reason for widespread use depends basically on that acesulfame is easily digested and is not deposited in the body. In addition, acesulfame used as ligands in transition metal complexes show thermochromic and solvatochromic properties. In this study, mixed ligand complex Mn(acs)2(H2O)4 was produced and crystallized and examined with EPR spectroscopy. Structure of the complex and behaviors at different temperatures were discussed.

References

  • [1] İçbudak H, Naumov P, Ristova M, Jovanovski G, 2002. Structural studies of bis(osulfobenzimidato)praseodymium(III) chloride hexahydrate. Journal of Molecular Structure, 606(1-3), 77-86.
  • [2] Çetin N, 2005. Synthesis, spectroscopic, thermal and chromotropic properties of some acesulfame-transition metal complexes. Ondokuz Mayıs University Graduate School of Sciences Master’s thesis, Samsun.
  • [3] İcbudak H, Adıyaman E, Cetin N, 2006. Synthesis, structural characterization and chromotropism of a Ni(II) and a Co(II) compound with acesulfamate as a ligand. Transit. Met. Chem., 31: 666-672.
  • [4] Abragam A, Bleaney B, 1970. Electron Paramagnetic Resonance of Transition Ions. Oxford, England: Clarendon Press.
  • [5] Wertz JE, Bolton JR, 1972. Electron Spin Resonance. New York, NY, USA: Mc-Graw-Hill.
  • [6] Tapramaz R, 1991. Kükürt-oksi, metilsülfinil ve arsenat radikallerinin elektron spin rezonans spektroskopisi ile incelenmesi. Ondokuz Mayıs Üniversitesi, Fen Bilimleri Enstitüsü, Doktora tezi, PhD,Samsun.
  • [7] Chu KC, 1976. ESR of vanadyl-ion-doped ammonium sulfate single crystals. J. Magn. Reson., 21: 151-152.
  • [8] Mısra SK, Wang C, 1989. EPR of VO+2 in Cd(COO)2.3H2O single Crystal: Superhyperfine Iteraction With Ligan Protons, Physica B., 159: 321-329.
  • [9] Venkateshwarlu M, Rao TB, 1992. EPR Study of VanadylIon in Tripotassium Citrate. Solid State Comm., 32: 837-839.
  • [10] Liu TK, Yu JT, Lao SH, Lee CH, Huang Y, Lii KH J, 1994. Electron Paramagnetic Resonance Study of V+4-Doped KTiOPO4 Single Crystal. J. Phys. Solids, 55: 1221-1226.
  • [11] Jayebalan T, Sami P, Shunmugasundavam A, Murugesan R, 1999. EPR Study of Mn(II)-doped CoH6CeMo12O42.12H2O: host Site Symmetryand Spin-lattice Relaxation Time. Spectroc. Acta A, 55: 2187-2193.
  • [12] Padiyan DP, Muthukrishnan C, Murugesan R, 2002. SingleCrystal EPR Studies Mn(II)-doped Sarcasine Cadmium Chlorideand Sarcosine Cadmium Bromide Study of Zero-FieldSplittingTensor in so-Structural Complexes. Spectroc. Acta A, 58: 509-517.
  • [13] Fidan M, Icbudak H, Tapramaz R, Sahin Y, 2011. Thermaland EPR spectroscopic studies of novel coordination compoundtransbis(acesulfamato)tetraaquazinc(II) with Mn(II) impurity. Spectroc. Acta A, 79(1): 17-20.

Mn+2 katkılı [Mn(acs)2(H20)4] Asesülfam Metal Kompleksinin Epr Spektroskopisi ile İncelenmesi

Year 2020, Volume: 5 Issue: 1, 49 - 54, 18.06.2020
https://doi.org/10.33484/sinopfbd.660660

Abstract

Bu çalışmada Mn+2 katkılı [Mn(acs)2(H2O)4] asesülfam metal kompleksinin yapısı EPR spektroskopisi ile incelenmiştir. Geçiş metali iyon kompleksleri hem bilim hem de teknolojide önemli uygulamalara sahiptir. Bu komplekslerin bazıları, paramanyetik metal iyonları Mn+2, VO+2, Cu+2, Fe+3, Cr+3 kullanılarak oluşturulur ve yapısal bilgi sağlamak için EPR spektroskopisi ile analiz edilir. Sentetik tatlandırıcı asesülfam, gıda, tıp ve kozmetikte yaygın şekilde kullanılır. Yaygın kullanımın nedeni temel olarak asesülfamın kolayca sindirilmesine ve vücutta birikmemesine bağlıdır. Ek olarak, geçiş metali komplekslerinde ligandlar olarak kullanılan asesülfam, termokromik ve solvatokromik özellikler gösterir. Bu çalışmada, karışık ligandkompleksi Mn(acs)2(H2O)4 üretilmiş ve kristalleştirilmiştir. Daha sonra EPR spektroskopisi ile incelenmiştir. Kompleksin yapısı ve farklı sıcaklıklardaki davranışları tartışılmıştır.

References

  • [1] İçbudak H, Naumov P, Ristova M, Jovanovski G, 2002. Structural studies of bis(osulfobenzimidato)praseodymium(III) chloride hexahydrate. Journal of Molecular Structure, 606(1-3), 77-86.
  • [2] Çetin N, 2005. Synthesis, spectroscopic, thermal and chromotropic properties of some acesulfame-transition metal complexes. Ondokuz Mayıs University Graduate School of Sciences Master’s thesis, Samsun.
  • [3] İcbudak H, Adıyaman E, Cetin N, 2006. Synthesis, structural characterization and chromotropism of a Ni(II) and a Co(II) compound with acesulfamate as a ligand. Transit. Met. Chem., 31: 666-672.
  • [4] Abragam A, Bleaney B, 1970. Electron Paramagnetic Resonance of Transition Ions. Oxford, England: Clarendon Press.
  • [5] Wertz JE, Bolton JR, 1972. Electron Spin Resonance. New York, NY, USA: Mc-Graw-Hill.
  • [6] Tapramaz R, 1991. Kükürt-oksi, metilsülfinil ve arsenat radikallerinin elektron spin rezonans spektroskopisi ile incelenmesi. Ondokuz Mayıs Üniversitesi, Fen Bilimleri Enstitüsü, Doktora tezi, PhD,Samsun.
  • [7] Chu KC, 1976. ESR of vanadyl-ion-doped ammonium sulfate single crystals. J. Magn. Reson., 21: 151-152.
  • [8] Mısra SK, Wang C, 1989. EPR of VO+2 in Cd(COO)2.3H2O single Crystal: Superhyperfine Iteraction With Ligan Protons, Physica B., 159: 321-329.
  • [9] Venkateshwarlu M, Rao TB, 1992. EPR Study of VanadylIon in Tripotassium Citrate. Solid State Comm., 32: 837-839.
  • [10] Liu TK, Yu JT, Lao SH, Lee CH, Huang Y, Lii KH J, 1994. Electron Paramagnetic Resonance Study of V+4-Doped KTiOPO4 Single Crystal. J. Phys. Solids, 55: 1221-1226.
  • [11] Jayebalan T, Sami P, Shunmugasundavam A, Murugesan R, 1999. EPR Study of Mn(II)-doped CoH6CeMo12O42.12H2O: host Site Symmetryand Spin-lattice Relaxation Time. Spectroc. Acta A, 55: 2187-2193.
  • [12] Padiyan DP, Muthukrishnan C, Murugesan R, 2002. SingleCrystal EPR Studies Mn(II)-doped Sarcasine Cadmium Chlorideand Sarcosine Cadmium Bromide Study of Zero-FieldSplittingTensor in so-Structural Complexes. Spectroc. Acta A, 58: 509-517.
  • [13] Fidan M, Icbudak H, Tapramaz R, Sahin Y, 2011. Thermaland EPR spectroscopic studies of novel coordination compoundtransbis(acesulfamato)tetraaquazinc(II) with Mn(II) impurity. Spectroc. Acta A, 79(1): 17-20.
There are 13 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Mehpeyker Kocakoç 0000-0001-7966-1482

Hasan İçbudak 0000-0001-9969-2358

Recep Tapramaz 0000-0002-7051-1717

Publication Date June 18, 2020
Submission Date December 17, 2019
Published in Issue Year 2020 Volume: 5 Issue: 1

Cite

APA Kocakoç, M., İçbudak, H., & Tapramaz, R. (2020). Epr Spectroscopic Investigation of Mn+2 Acesulfam Metal Complex, [Mn(acs)2(H2O)4]. Sinop Üniversitesi Fen Bilimleri Dergisi, 5(1), 49-54. https://doi.org/10.33484/sinopfbd.660660