Research Article
Year 2020,
Volume: 24 Issue: 5, 1023 - 1028, 01.10.2020
Abstract
References
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- X. Huang, J. Guo, Q. An, X. Gong,Y. Gong, S. Zhang, “Preparation and characterization of di‐hexadecanol maleic/triallyl isocyanurate cross‐linked copolymer as solid–solid phase change materials,” J. Appl. Polym. Sci., vol. 133, no. 40, pp. 44065, 2016.
- W.R. Sorenson, T.W. Campbell, “Preparative Methods of Polymer Chemistry, Interscience Publishers,” New York, pp. 130- 154, 1968.
- S. Sundararajan , A. Kumar, B.C. Chakraborty, A.B.Samui and P.S. Kulkarni, “Poly(thylene glycol) (PEG)-modified epoxy phase-change polymer with dual properties of thermal storage and vibration damping,” Sust. Energ. Fuels, vol. 2, no. 3, pp. 688-697, 2018.
- Liu H.J., L.H. Lin, K.M. Chen, “Preparation and Properties of Water-Soluble Polyester Surfactants. III. Preparation and Wetting Properties of Polyethylene Glycol–Polydimethylsiloxane Polyester Surfactants,” Appl. Polym. Sci., vol. 88, no. 5, pp. 1236 –1241, 2003.
Synthesis and Characterization of Maleic Anhydride Modified Poly (Ethylene Glycol) as Polymeric Solid-Solid Phase Change Materials
Abstract
In this study, a novel type of polymeric solid-solid phase change materials (SSPCMs) and Maleic anhydride (MA) modified poly (ethylene glycol) PEG. MAM-PEG polymers were synthesized from different moleculer weight PEG (Mw: 4000, 6000) .On the other hand two different catalyst system was used; para toluene sulfonic acid (PTSA) and 1,8-Diazabicyclo [5.4.0] undec-7-ene (DBU).The PEG bound to the backbone of the polymers formed crystalline regions responsible from latent heat storage with reversible crystalline to amorphous phase transition as linked unit prevented total melting of the structure. Also MAM-PEG polyester polymers acid and hydroxyl values were determined for number of average molecular weight (Mn) and calculated as 36232 and 49020. Characterization and thermal properties of SSPCMs were performed by using fourier transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) techniques mainly. DSC results showed that solid-solid transitions 36-54 °C temperature range and 163-153 Jg-1 enthalpy. As a result, MAM-PEG polymers were found potential for thermal energy storage (TES) applications.
Keywords
References
- B Zalba., J.M. Marin, L.F. Cabeza and H. Mehling, “Review on thermal energy storage with phase change: materials, heat transfer analysis, and applications,” Appl. Therm. Eng., vol. 23, no. 3, pp. 251–283, 2003.
- M. Kenisarin, K. Mahkamov, “Solar energy storage using phase change materials,” Renew. Sust. Energy Rev., vol. 11, no. 9, pp. 1913–1965, 2007.
- C. Chen, L. Wang, Y. Huang, “Crosslinking of the electrospun polyethylene glycol/ cellulose acetate composite fibers as shape-stabilized phase change materials," Mater. Lett., vol. 63, no. 5, pp. 569-571, 2009.
- C. Chen, L. Wang, Y. Huang, “Morphology and thermal properties of electrospun fatty acids/polyethylene terephthalate composite fibers as novel form-stable phase change materials,” Sol. Energ. Mater. Sol. Cells, vol. 92, no. 11, pp. 1382-1387, 2008.
- M. Li, Z. Wu, H. Kao, “Study on preparation and thermal properties of binary fatty acid/diatomite shape-stabilized phase change materials,” Sol. Energy Mater. Sol. Cells, vol. 95, no. 8, pp. 2412–2416, 2011.
- Y. Wang, A. Yuan, Y. Zhao, Q Liu., J. Lei, “Phase change material with flexible crosslinking for thermal energy storage,” J. Appl. Polym. Sci., vol. 137, no. 13, pp. 48497, 2020.
- S. Sundararajan, A.B. Samui, i P.S. Kulkarni “Versatility of polyethylene glycol (PEG) in designing solid-solid phase change materials (PCMs) for thermal management and their application to innovative technologies,” J. Mater. Chem.A, vol. 5, no. 35, pp. 18379-18396, 2017.
- L. Liu, L. Kong, H. Wang, R. Niu, H. Shi, “Effect of graphene oxide nanoplatelets on the thermal characteristics and shape-stabilized performance of poly(styrene-co-maleic anhydride)-g-octadecanol comb-like polymeric phase change materials,” Sol. Energ. Mater. Sol. Cells, vol. 149, pp. 40-48, 2016.
- X. Fu, W. Kong, Y. Zhang, L. Jiang, J Wang., J. Lei, “Novel solid–solid phase change materials with biodegradable trihydroxy surfactants for thermal energy storage,” RSC Adv., vol. 5, no. 84, pp. 68881–68889, 2015.
- Y. Jiang, E. Ding, G. Li, “Study on transition characteristics of PEG/CDA solid– solid phase change materials,” Polymer, vol. 43, no. 1, pp. 117–122, 2002.
- Y.N. Zang, E.Y. Ding, “Energy storage properties of phase change materials prepared from PEG/CPP,” Chin. Chem. Lett., vol. 16, no. 10, pp. 1375–1378, 2005.
- X.H. Liang, Y.Q. Guo, L.Z. Gu, E.Y. Ding, “Crystalline–amorphous phase- transition of a poly(ethylene glycol) cellulose blend,” Macromolecules, vol. 28, no. 19, pp. 6551–6555, 1995.
- X.P. Yuan, E.Y. Ding, “Synthesis and characterization of storage energy materials prepared from nano-crystalline cellulose/polyethylene glycol,” Chin. Chem. Lett., vol. 17, no. 8, pp. 1129–1132, 2006.
- M. Zhang, Y. Na, Z.H. Jiang, “Preparation and properties of polymeric solid–solid phase change materials of polyethylene glycol (PEG)/poly(vinyl alcoho1) (PVA) copolymers by graft copolymerization,” Chem. J. Chin. Univ., vol. 26, no.1, pp. 170–174, 2005.
- A. Sarı, A. Biçer, C. Alkan, “Thermal energy storage characteristics of poly(styrene-co-maleic anhydride)-graft-PEG as polymeric solid–solid phase change materials,” Sol. Energ. Mater. Sol. Cells, vol. 161, pp. 219–225, 2017.
- X. Huang, J. Guo, Q. An, X. Gong,Y. Gong, S. Zhang, “Preparation and characterization of di‐hexadecanol maleic/triallyl isocyanurate cross‐linked copolymer as solid–solid phase change materials,” J. Appl. Polym. Sci., vol. 133, no. 40, pp. 44065, 2016.
- W.R. Sorenson, T.W. Campbell, “Preparative Methods of Polymer Chemistry, Interscience Publishers,” New York, pp. 130- 154, 1968.
- S. Sundararajan , A. Kumar, B.C. Chakraborty, A.B.Samui and P.S. Kulkarni, “Poly(thylene glycol) (PEG)-modified epoxy phase-change polymer with dual properties of thermal storage and vibration damping,” Sust. Energ. Fuels, vol. 2, no. 3, pp. 688-697, 2018.
- Liu H.J., L.H. Lin, K.M. Chen, “Preparation and Properties of Water-Soluble Polyester Surfactants. III. Preparation and Wetting Properties of Polyethylene Glycol–Polydimethylsiloxane Polyester Surfactants,” Appl. Polym. Sci., vol. 88, no. 5, pp. 1236 –1241, 2003.
There are 19 citations in total.
Details
| Primary Language | English |
|---|---|
| Subjects | Material Production Technologies |
| Journal Section | Research Articles |
| Authors | |
| Publication Date | October 1, 2020 |
| Submission Date | January 22, 2020 |
| Acceptance Date | August 4, 2020 |
| Published in Issue | Year 2020 Volume: 24 Issue: 5 |
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Sakarya University Journal of Science (SAUJS)