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Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler

Year 1996, Volume: 9 Issue: 2, 53 - 68, 31.12.1996

Hürriyet Erşahan O. Nuri Şara

Abstract

Pirall:. kaılll'ırilll ga: ve sıvı urüııler vermek ü:ere ısıl bo:ıındunılnıası
islnııırlirUys. ıılamada yııvaş ve çabuk fiını/i: olmak ikere iki pırolı: yöııremi
vardır. Köıııiırleriıı etkili hıllaıımıı ve ly/leflinlıııesi açisindan çalıuk. (flash) piroli: yararlı
bir yöıılnndır. Blııııııı yaıııııda, (flash) pıroli: yııınna ve ga:lastırma gibi pek çok kömür
r/oıı/isüııı prosesiıııie öııvnıli bir ilk basamaklır. Pirolı: soııııııda elde edilen sıvı ürün çok
sayıda bile'jcıı ifi'ıvıı değerli hır lirinıdiir, kail vrSnün ise gadastırnıa gibi başka
prosesierfk de^ertesujtrUmes! miimkvnchır.

Keywords

kömür piroliz çabuk piroliz

References

  • [1] J0wen. "Conversion aııd uses of liquid fuels from coal", Fııel, vol. 65, pp. 755-761, 1981.
  • [2] J. B. Howard, Chemislry ofCoal Ulili:atioıı, (Ed. M. A. EIliolt), 12. Bölüm, Jolm Wiley and Sons, 1981
  • [3] l. Wendcr, "Coal science in changing ıvorld". /. '»e/. vol. 64, pp. 1035-1038. 1985.
  • [4] K. C. Teo, A. P, Watkiusou, Rapid pyrolysis ofCanadiaü coals in a miniature spouted bed reactor". Fuel. vol. 65, pp. 949-959, 1986.
  • [5] J W. X. Chun, A. Tomita, "Effeet ofcoal type on tlıe flash pyroİysis ofvanous coals", Fuel, vol. 66, pp. 627-631, 1987.
  • [6] H. Jüngteu, "Re\'iew of kiuetics ol pyrolysis and hydropyroîysis in relation to the chemical coııslılution of co al , Fî<el, vol. 63, pp. 731-737, 1984.
  • [7] P. L. Jr. Wa1keı-, "StmctLire of Cüals and their coversion to gaseous coals, Fııei, vol. 60, pp. 802-802, 1981.
  • [8] Chun W;ıi Lee. Alaıı W. Scaroni, Robeıt G. Jeukins, "Effect of pressure on Uıe devolatilization and swel1ing bebaviour of a softening coaî durmg rapid heating" Fî<ei, vol70. pp. 957-965, 1991.
  • [9] P. R. Solomon, T. H. Fletclıer, R. J. Pugiüü'e, "Progı'ess iıı coal pyrolysis", Fî/e/, vol, 72, no. 5, p|). 587-597, 1993.
  • [10] Wang Jie, Cao Yuqun, Yan Yongjie, Gao Jiıısheng, "Heat transfer aud kinetıcs ofügıute devoladüzation in vvire-mesh apparatus , Fuel Processhıg Techonology, vo1, 38, pp. 57-67, 1994.
  • [11] ZlıihUft Ma, Zibiu Zhu, Chengfang Zlıaııg, Hamhuya Jiıı. "Flaslı tıydropyrolysis of Zaîamıoer ligııite", Fue/ Processıg Techonofog\:vo\, 3^, pp. 99-109, 1994.
  • [12] P. R. Solomon, D. G. Hamblen, R. M. Carangelo, M. A. Serio, G. V. Desbpande, "A general model of coal devoiatiJization", ACS, Div. of Fîiel Chem. Preprinî, vol. 32. no. 2, pp. 83-88, 1987.
  • [13] P. J. J. Tromp, J. A. Moulıjn, S!o\v and raptd pyrotysis of coal, New Trends in Coal Science, NATO ASI, D. Reidel Pub. Co.. 1988.
  • [14] C. Y, Wen, S. Dutta, Coal Conversion Techno/ogy, Addlson Wesley Publishing Co., Massachusetts. 1979.
  • [15] M. Stemberg, The flash pyrotys is aııd hydropyrotys ıs of coal. Atlantic Research Lab., Report 110:30. Canada, 1982.
  • [16] N. Nsakal, P. L. )r. Walker, R. H. Essenlıingb, "Clıaıacteıisics of chaıs produced by pyrolysis folloıving rapid hearing ofpulveıized coals". U. S. Dep. ofEnergy, Technical Report 2, 1987.
  • [17] H. Jüngten. K. H.Van Heek, "An updata ofGeman ııon-isotennal coal pyrolysis work". Fvel Pıvcessıng Technology, vol. 2, pp. 261-293. 1979.
  • [18] D. S. Scott, J. Ppiskoı-z, "Pyrolysis of low rank Canadiaü coals", Fııe! Processmg Techonolgy, vol. l3. pp. 157. 186. 1986.
  • [19] RJ. Tyler, "Flaslı pyrolysis coals: DevolatilLzation of bituminous coals m a small fluidized bed reactor". Fııel, vol. 59, pp. 218-226, 1980.
  • [20] P. Cone, V.Herault, S. Castmo, J.P. Tıaverse, "High temperature gasification of carbonaceous materials by flash pyrolysis: tlıeı-mal aspects", Fııel. vol. 66, pp, 1107-1114, 1987.
  • [21] H. I. Sroith, G.J.Wenıer, Coal Coııversion Techmlogy', Noyes Data CoiToration, 1976.
  • [22] R. S. Tpn'est, P. Vaıı Meurs, "Laboratoı-y studies of the rapid pyrolysis and desulphurizatiön ofTexas]igl"te",./-ue/, vol. 59, pp. 458-464, 1980.
  • [23] S. Badzioclı, P. G. W. Hawksley, "Kinetics of theıınal decomposition pulverized coal particles". Ind. Eng. Chem. Process Des. Dev.. vol. 9. no. 4, pp. 521-530, 1970.
  • [24] S. Badzioch, "Rapid and controlled decomposition of coal".. The Brilish Coal Utı/üatioıı Research Associalion, vol. 25. no. 8, pp. 285-301. 1961.
  • [25] G. R. Gavalas, Coal Science aııd leclmology 4: Coal Pyrolysis, Elscvier, 1982,
  • [26] D.B. Anthony, J. B.Howard, "Coal devolatilization aııd hydrogasification", AIChE, vol. 22, p)). 625-656, 1976.
  • [27] D. B. Anllıony, J.B.Howard, H. C. Hottel, H. P. Meissneı, "Rapitl devolatilization of pulverized coal", 15. Int. Symp.on Combustion. Tlıe Combustion Iııstitute, Pinsburgh. 1974.
  • [28] E. M. Suııberg, l'. E.Unger. W. D. Lilly, "Expenmeııtal study on nıass traıısfer fi'onı pyrolysing coal particles", Fvel, vol. 64, pp. 956-962, 1974
  • [29] Ü.B.Anthony, J. B. Hon'ard, H. CHottel, H. P. Meissner, "Kapid devolatilizatıoi] aııd hydrogasifıcation ofbituminous coal , Fue!. vo\. 55, pp. 121-128, 1976,
  • [30] J. Uolınson. Kinefıcs ofCoal Gasiflccıîion, Jolın Witey and Soııs, New York. 1979,
  • [31] E. M. Sımberg, W.A. Peters, J. B. Howard. Product composilioıı in rapid lıydropyroiysis ofcoal". Fîfe/. vol. 59. pp 405-412, 1980.
  • [32] J. F. Jones, M. R. Sİmııd, R. T. Eddmger, "1'lıe thermal decomposıtioıı of coaİ". Chem. EHg. Progress, voî. 60, 110. 6, pp, 69-73, 1964.
  • [33] E. M. Suuberg, W.A. Peteı-s, J. B. Howard, "Pruducî composİtion and kinetis af ligııite pyrolysis", /ICS Div. ofFııel Chemistry. I'reprint 22(1), pp. l 12-136, 1977.
  • [34] H. Erşahan, Beypazarı Lifiyıf/erjnhı Çabtik(pa sh) Pirohzi, Doktora Tezi, Ankara Univ.Fen Bfl. Enst., Ankara, 198S.
  • [35] G. R. Gavalas, K. A. Wilks, AIChEJ. vol. 26, pp. 201-212, 1980.
  • [36] M. E. Moı-gan, R. GJenkins, "Pyrolysis of îigııite in an eııtraiued-f1ow 3'eactor", Fae/, vol. 65, pp. 757-763, 19S6.
  • [37] W. S. Bnen, J, W. Clıen, A. Moslehi, R. C. R. Wu. "Kİnetic modellİııg ofcoal pyroîysis iîi a laminar-floıv reactor", ACS Div. ofFvel Chem., Preprint 32(3), pp. 99-104, 1987.
  • [38] L. Coîiti, "Flash Pyrolsis of an Italian Low Rank Coaî, Fı/e/ Processnıg Techadog).; vol. l7, pp. 101-1 15, 1987.
  • [39] Z. S, Gönenç, Jon. R. Gibbins, l, E. K atlı ekt akis, and R. Kaudiyoti, "Compansion of coat pyrolsis product dİstnbutions from tree capalive sample techüiques, Fîief, vol. 69, pp. 383- 390. 1990.

Flash Pyrolysis Of Coals And Experimental Techniques

Year 1996, Volume: 9 Issue: 2, 53 - 68, 31.12.1996

Hürriyet Erşahan O. Nuri Şara

Abstract

Pmlysis caıı be described as ıhe Ihennal decomposılıon of coals which

resıılf. ': ııı ılır ıvlc'asr of gaseoııs cıııd 1/yıı/d prodııcls. Sil practlce, Ihere are lwo py'rolysis

ııınhoıls: siow nııd flıısh pyrolysıs. Flash pyrolysıs of coals ıs very vseful method for

rffertive lise aııcl ıı/iffrnılıııg o/'roals, alici ıs aıı ımponaııl prelinıiııary step ili Ihc mast coal

cnııvvrsıoıı processes sııch as coıııljııstıoıı aıld gasi/icalioıı 'i'he lıqviıi yie/d obtaimd from

pvrnlysis coıılıııııs u yvr. l ıııııııber of conıpouııds aııcl is a valııab/e prodvcl The char can

he ısseii aı oîhvr proci^:\es sach cıs gasifıcctfioa.

Keywords

coal pyrolysis flash pyrolysis

References

  • [1] J0wen. "Conversion aııd uses of liquid fuels from coal", Fııel, vol. 65, pp. 755-761, 1981.
  • [2] J. B. Howard, Chemislry ofCoal Ulili:atioıı, (Ed. M. A. EIliolt), 12. Bölüm, Jolm Wiley and Sons, 1981
  • [3] l. Wendcr, "Coal science in changing ıvorld". /. '»e/. vol. 64, pp. 1035-1038. 1985.
  • [4] K. C. Teo, A. P, Watkiusou, Rapid pyrolysis ofCanadiaü coals in a miniature spouted bed reactor". Fuel. vol. 65, pp. 949-959, 1986.
  • [5] J W. X. Chun, A. Tomita, "Effeet ofcoal type on tlıe flash pyroİysis ofvanous coals", Fuel, vol. 66, pp. 627-631, 1987.
  • [6] H. Jüngteu, "Re\'iew of kiuetics ol pyrolysis and hydropyroîysis in relation to the chemical coııslılution of co al , Fî<el, vol. 63, pp. 731-737, 1984.
  • [7] P. L. Jr. Wa1keı-, "StmctLire of Cüals and their coversion to gaseous coals, Fııei, vol. 60, pp. 802-802, 1981.
  • [8] Chun W;ıi Lee. Alaıı W. Scaroni, Robeıt G. Jeukins, "Effect of pressure on Uıe devolatilization and swel1ing bebaviour of a softening coaî durmg rapid heating" Fî<ei, vol70. pp. 957-965, 1991.
  • [9] P. R. Solomon, T. H. Fletclıer, R. J. Pugiüü'e, "Progı'ess iıı coal pyrolysis", Fî/e/, vol, 72, no. 5, p|). 587-597, 1993.
  • [10] Wang Jie, Cao Yuqun, Yan Yongjie, Gao Jiıısheng, "Heat transfer aud kinetıcs ofügıute devoladüzation in vvire-mesh apparatus , Fuel Processhıg Techonology, vo1, 38, pp. 57-67, 1994.
  • [11] ZlıihUft Ma, Zibiu Zhu, Chengfang Zlıaııg, Hamhuya Jiıı. "Flaslı tıydropyrolysis of Zaîamıoer ligııite", Fue/ Processıg Techonofog\:vo\, 3^, pp. 99-109, 1994.
  • [12] P. R. Solomon, D. G. Hamblen, R. M. Carangelo, M. A. Serio, G. V. Desbpande, "A general model of coal devoiatiJization", ACS, Div. of Fîiel Chem. Preprinî, vol. 32. no. 2, pp. 83-88, 1987.
  • [13] P. J. J. Tromp, J. A. Moulıjn, S!o\v and raptd pyrotysis of coal, New Trends in Coal Science, NATO ASI, D. Reidel Pub. Co.. 1988.
  • [14] C. Y, Wen, S. Dutta, Coal Conversion Techno/ogy, Addlson Wesley Publishing Co., Massachusetts. 1979.
  • [15] M. Stemberg, The flash pyrotys is aııd hydropyrotys ıs of coal. Atlantic Research Lab., Report 110:30. Canada, 1982.
  • [16] N. Nsakal, P. L. )r. Walker, R. H. Essenlıingb, "Clıaıacteıisics of chaıs produced by pyrolysis folloıving rapid hearing ofpulveıized coals". U. S. Dep. ofEnergy, Technical Report 2, 1987.
  • [17] H. Jüngten. K. H.Van Heek, "An updata ofGeman ııon-isotennal coal pyrolysis work". Fvel Pıvcessıng Technology, vol. 2, pp. 261-293. 1979.
  • [18] D. S. Scott, J. Ppiskoı-z, "Pyrolysis of low rank Canadiaü coals", Fııe! Processmg Techonolgy, vol. l3. pp. 157. 186. 1986.
  • [19] RJ. Tyler, "Flaslı pyrolysis coals: DevolatilLzation of bituminous coals m a small fluidized bed reactor". Fııel, vol. 59, pp. 218-226, 1980.
  • [20] P. Cone, V.Herault, S. Castmo, J.P. Tıaverse, "High temperature gasification of carbonaceous materials by flash pyrolysis: tlıeı-mal aspects", Fııel. vol. 66, pp, 1107-1114, 1987.
  • [21] H. I. Sroith, G.J.Wenıer, Coal Coııversion Techmlogy', Noyes Data CoiToration, 1976.
  • [22] R. S. Tpn'est, P. Vaıı Meurs, "Laboratoı-y studies of the rapid pyrolysis and desulphurizatiön ofTexas]igl"te",./-ue/, vol. 59, pp. 458-464, 1980.
  • [23] S. Badzioclı, P. G. W. Hawksley, "Kinetics of theıınal decomposition pulverized coal particles". Ind. Eng. Chem. Process Des. Dev.. vol. 9. no. 4, pp. 521-530, 1970.
  • [24] S. Badzioch, "Rapid and controlled decomposition of coal".. The Brilish Coal Utı/üatioıı Research Associalion, vol. 25. no. 8, pp. 285-301. 1961.
  • [25] G. R. Gavalas, Coal Science aııd leclmology 4: Coal Pyrolysis, Elscvier, 1982,
  • [26] D.B. Anthony, J. B.Howard, "Coal devolatilization aııd hydrogasification", AIChE, vol. 22, p)). 625-656, 1976.
  • [27] D. B. Anllıony, J.B.Howard, H. C. Hottel, H. P. Meissneı, "Rapitl devolatilization of pulverized coal", 15. Int. Symp.on Combustion. Tlıe Combustion Iııstitute, Pinsburgh. 1974.
  • [28] E. M. Suııberg, l'. E.Unger. W. D. Lilly, "Expenmeııtal study on nıass traıısfer fi'onı pyrolysing coal particles", Fvel, vol. 64, pp. 956-962, 1974
  • [29] Ü.B.Anthony, J. B. Hon'ard, H. CHottel, H. P. Meissner, "Kapid devolatilizatıoi] aııd hydrogasifıcation ofbituminous coal , Fue!. vo\. 55, pp. 121-128, 1976,
  • [30] J. Uolınson. Kinefıcs ofCoal Gasiflccıîion, Jolın Witey and Soııs, New York. 1979,
  • [31] E. M. Sımberg, W.A. Peters, J. B. Howard. Product composilioıı in rapid lıydropyroiysis ofcoal". Fîfe/. vol. 59. pp 405-412, 1980.
  • [32] J. F. Jones, M. R. Sİmııd, R. T. Eddmger, "1'lıe thermal decomposıtioıı of coaİ". Chem. EHg. Progress, voî. 60, 110. 6, pp, 69-73, 1964.
  • [33] E. M. Suuberg, W.A. Peteı-s, J. B. Howard, "Pruducî composİtion and kinetis af ligııite pyrolysis", /ICS Div. ofFııel Chemistry. I'reprint 22(1), pp. l 12-136, 1977.
  • [34] H. Erşahan, Beypazarı Lifiyıf/erjnhı Çabtik(pa sh) Pirohzi, Doktora Tezi, Ankara Univ.Fen Bfl. Enst., Ankara, 198S.
  • [35] G. R. Gavalas, K. A. Wilks, AIChEJ. vol. 26, pp. 201-212, 1980.
  • [36] M. E. Moı-gan, R. GJenkins, "Pyrolysis of îigııite in an eııtraiued-f1ow 3'eactor", Fae/, vol. 65, pp. 757-763, 19S6.
  • [37] W. S. Bnen, J, W. Clıen, A. Moslehi, R. C. R. Wu. "Kİnetic modellİııg ofcoal pyroîysis iîi a laminar-floıv reactor", ACS Div. ofFvel Chem., Preprint 32(3), pp. 99-104, 1987.
  • [38] L. Coîiti, "Flash Pyrolsis of an Italian Low Rank Coaî, Fı/e/ Processnıg Techadog).; vol. l7, pp. 101-1 15, 1987.
  • [39] Z. S, Gönenç, Jon. R. Gibbins, l, E. K atlı ekt akis, and R. Kaudiyoti, "Compansion of coat pyrolsis product dİstnbutions from tree capalive sample techüiques, Fîief, vol. 69, pp. 383- 390. 1990.
There are 39 citations in total.

Details

Journal Section Research Articles
Authors

Hürriyet Erşahan

O. Nuri Şara

Publication Date December 31, 1996
Acceptance Date July 1, 1996
Published in Issue Year 1996 Volume: 9 Issue: 2

Cite

APA Erşahan, H., & Şara, O. N. (1996). Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 9(2), 53-68.
AMA Erşahan H, Şara ON. Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler. ESOGÜ Müh Mim Fak Derg. December 1996;9(2):53-68.
Chicago Erşahan, Hürriyet, and O. Nuri Şara. “Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 9, no. 2 (December 1996): 53-68.
EndNote Erşahan H, Şara ON (December 1, 1996) Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 9 2 53–68.
IEEE H. Erşahan and O. N. Şara, “Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler”, ESOGÜ Müh Mim Fak Derg, vol. 9, no. 2, pp. 53–68, 1996.
ISNAD Erşahan, Hürriyet - Şara, O. Nuri. “Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 9/2 (December 1996), 53-68.
JAMA Erşahan H, Şara ON. Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler. ESOGÜ Müh Mim Fak Derg. 1996;9:53–68.
MLA Erşahan, Hürriyet and O. Nuri Şara. “Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, vol. 9, no. 2, 1996, pp. 53-68.
Vancouver Erşahan H, Şara ON. Kömürlerin Flash Pirolizi Ve Kullanılan Deneysel Teknikler. ESOGÜ Müh Mim Fak Derg. 1996;9(2):53-68.
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