Research Article
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Year 2019, Volume: 14 Issue: 4, 183 - 192, 30.12.2019

Abstract

References

  • Allafchian, A., Mousavi, Z. S., Hosseini, S. S., (2019) Application of cress seed musilage magnetic nanocomposites for removal of methylene blue dye from water, Int J Biol Macromol 136, 199-208.
  • Bedin, K. C., Martins, A. C., Cazetta, A. L., Pezoti, O., Almeida, V. C., (2016) KOH-activated carbon prepared from sucrose spherical carbon: Adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chemical Engineering Journal, 286, 476-484.
  • Caparkaya, D., Cavas. L., (2008) Biosorption of methylene blue by a brown alga Cystoseirabarbatula Kutzing. Acta Chimia Slovakia, 55, 547-553.
  • Cherifi, H., Fatiha, B., Salah, H., (2013) Kinetic studies on the adsorption of methylene blue onto vegetal fiber activated carbons. Applied Surface Science, 282, 52-59.
  • Crini, G., (2006) Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology, 97(9), 1061-1085.
  • Dawood, S., Sen, T. K., (2012) Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res, 46(6), 1933-46.
  • Debnath, S., Ballav, N., Maity, A., Pillay, K., (2017) Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin. Journal of Molecular Liquids, 225, 679-688.
  • Demirak, A., Keskin, F., Şahin, Y., Kalemci, V., (2015) Removal of ammonium from water by cone powder as biosorbent. Mugla Journal of Science and Technology, 1(1), 5-12.
  • El-Sikaily, A., Khaled, A., El-Nemr, A., Abdelwahab, O., (2006) Removal of methylene blue from aqueous solution by marine green alga ulva lactuca. Chemical Ecology, 22(2), 149-157.
  • Forgacs E., Cserhati T., Oros G., (2004) Removal of synthetic dyes from wastewaters: a review. Environment International, 30, 953-971.
  • Fu, Y., Viraraghavan, T., (2000) Removal of a dye from an aqueous solution by the fungus Aspergillus niger. Water Quality Research Journal, 35(1), 95-111.
  • Ghaedi, M., Hajjati. S., Mahmudi, Z., Tyagi, I., Agarwal, S., Maity, A., Gupta, V. K., (2015) Modeling of competitive ultrasonic assisted removal of the dyes – methylene blue and safranin-O using Fe3O4 nanoparticles. Chemical Engineering Journal, 268, 28-37.
  • Gouamid, M., Ouahrani, M. R., Bensaci, M. B., (2013) Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Energy Procedia, (36), 898-907.
  • Gupta V. K., Suhas, (2009) Application of low-cost adsorbents for dye removal – A review. Journal of Environmental Management, 90, 2313-2342.
  • Hamed, M. M., Ahmed, I. M., Metwally, S. S., (2014) Adsorptive removal of methylene blue as organic pollutant by marble dust as eco-friendly sorbent J Ind Eng Chem 20, 2370-2377.
  • Immaculate, L. A., Ouma, E. B. N., Ofomaja, A. E., (2018) Thermodynamic, kinetic and spectroscopic investigation of arsenite adsorption mechanism on pine cone-magnetite composite. Journal of Environmental Chemical Engineering, 6, 5409-5419.
  • Jian, Z., Qingwei, P., Meihong, N., Haiqiang, S., Na, L., (2013) Kinetics and equilibrium studies from the methylene blue adsorption on diatomite treated with sodium hydroxide. Applied Clay Science, 83, 12-16.
  • Jin, Y., Zeng, C., Lü, Q.-F., Yu, Y., (2019) Efficient adsorption of methylene blue and lead ions in aqueous solutions by 5-sulfosalicylic acid modified lignin. International Journal of Biological Macromolecules, 123, 50-58.
  • Kausar, A., Iqbal, M., Javeda, A., Aftab, K., Nazli, Z. H., Bhatti, H. N., Nouren, S., (2018) Adsorption Using Clay and Modified Clay: A Review. Journal of Molecular Liquids, 256, 395-407.
  • Kul, A. R., Aldemir. A., (2019) Comparison of Methylene Blue Adsorption Performance on Natural, Thermal and Acid Modified Kaolin: Isotherm, Kinetics and Thermodynamics Studies. Fresenius Environmental Bulletin, 28(6), 4475-4483.
  • Kul A. R, Koyuncu. H., (2010) Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: Kinetic, equilibrium and thermodynamic study. J Hazard Mater, 179, 332-339.
  • Kupeta, A. J. K., Naidoo, E. B., Ofomaja, A. E. (2018) Kinetics and equilibrium study of 2-nitrophenol adsorption onto polyurethane cross-linked pine cone biomass. Journal of Cleaner Production, 179, 191-209.
  • Mahmoodi, N. M., Hayati, B., Arami, M., Lan, C., (2011) Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination, 268(1-3), 117-125.
  • Martín-Lara, M. A., Blazquez, G., Calero, M., Almendros, A. I., Ronda, A., (2016) Binary biosorption of copper and lead onto pine cone shell in batch reactors and in fixed bed columns. International Journal of Mineral Processing, 148, 72-82.
  • Miyah, Y., Lahrichi, A., Idrissi, M., Khalil A., Zerrouq, F., (2018) Adsorption of methylene blue dye from aqueous solutions onto walnut shells powder: Equilibrium and kinetic studies Surfaces And Interfaces, 11 (1), 74–81.
  • Mtshatsheni, K. N. G. Ofomaja A. E., Naidoo, E. B., (2019) Synthesis and optimization of reaction variables in the preparation of pinemagnetite composite for removal of methylene blue dye. South African Journal of Chemical Engineering, 29, 33-41.
  • Ofomaja, A. E., Naidoo, E. B., Modise, S. J., (2009) Removal of copper(II) from aqueous solution by pine and base modified pine cone powder as biosorbent. J Hazard Mater, 168 (2-3), 909-17.
  • Ofomaja, A. E., Naidoo, E. B., Modise, S. J., (2010) Biosorption of copper(II) and lead(II) onto potassium hydroxide treated pine cone powder. J Environ Manage, 91(8), 1674-85.
  • Ofomaja, A. E., Naidoo, E. B., (2010) Biosorption of lead(II) onto pine cone powder: Studies on biosorption performance and process design to minimize biosorbent mass. Carbohydrate Polymers, 82(4), 1031-1042.
  • Rafatullah, M., Sulaiman, O., Hashim, R., Ahmad, A., (2010) Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater, 177(1-3), 70-80.
  • Rida, K., Bouraoui, S., Hadnine, S., (2013) Adsorption of methylene blue from aqueous solution by kaolin and zeolite. Applied Clay Science, 83, 99-105.
  • Salleh, M. A. M., Mahmoud, D. K., W. A. W. AbdulKarim, A. Idris, (2011) Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination, 280(1-3), 1-13.
  • Yagub, M. T., Sen T. K., Afroze, S., Ang, H. M, (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interface Sci, 209, 172-84.

Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder

Year 2019, Volume: 14 Issue: 4, 183 - 192, 30.12.2019

Abstract

In this study, the usage of pine
cone powder as an adsorbent for removing methylene blue from aqueous solution
was investigated. Within this scope adsorption experiments were performed and
the results showed that the Freundlich isotherm model was a more convenient
option compared to the Langmuir and Temkin models. The results also determined that
the pseudo second order kinetic model demonstrated higher correlation
coefficients (R2) values compared to the pseudo first order and
intra-particle diffusion models. Initial dye concentration was found to shift
from 100 to 300 mg/l, while adsorption capacity onto the pine cone powder
changed from 40.99 to 95.24 mg/g, 41.56 to 97.93 mg/g, and 43.51 to 101.41 mg/g
for 298 K, 308 K and 318 K, respectively. The thermodynamic parameters for the
instant free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) of this separation process
were found by referring to -1595,11 J/mol, 2465,83 J/mol and 12,77 J/mol,
respectively. The negative ΔGvalues revealed that this separation process
was endothermic and natural.

References

  • Allafchian, A., Mousavi, Z. S., Hosseini, S. S., (2019) Application of cress seed musilage magnetic nanocomposites for removal of methylene blue dye from water, Int J Biol Macromol 136, 199-208.
  • Bedin, K. C., Martins, A. C., Cazetta, A. L., Pezoti, O., Almeida, V. C., (2016) KOH-activated carbon prepared from sucrose spherical carbon: Adsorption equilibrium, kinetic and thermodynamic studies for methylene blue removal. Chemical Engineering Journal, 286, 476-484.
  • Caparkaya, D., Cavas. L., (2008) Biosorption of methylene blue by a brown alga Cystoseirabarbatula Kutzing. Acta Chimia Slovakia, 55, 547-553.
  • Cherifi, H., Fatiha, B., Salah, H., (2013) Kinetic studies on the adsorption of methylene blue onto vegetal fiber activated carbons. Applied Surface Science, 282, 52-59.
  • Crini, G., (2006) Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology, 97(9), 1061-1085.
  • Dawood, S., Sen, T. K., (2012) Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res, 46(6), 1933-46.
  • Debnath, S., Ballav, N., Maity, A., Pillay, K., (2017) Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin. Journal of Molecular Liquids, 225, 679-688.
  • Demirak, A., Keskin, F., Şahin, Y., Kalemci, V., (2015) Removal of ammonium from water by cone powder as biosorbent. Mugla Journal of Science and Technology, 1(1), 5-12.
  • El-Sikaily, A., Khaled, A., El-Nemr, A., Abdelwahab, O., (2006) Removal of methylene blue from aqueous solution by marine green alga ulva lactuca. Chemical Ecology, 22(2), 149-157.
  • Forgacs E., Cserhati T., Oros G., (2004) Removal of synthetic dyes from wastewaters: a review. Environment International, 30, 953-971.
  • Fu, Y., Viraraghavan, T., (2000) Removal of a dye from an aqueous solution by the fungus Aspergillus niger. Water Quality Research Journal, 35(1), 95-111.
  • Ghaedi, M., Hajjati. S., Mahmudi, Z., Tyagi, I., Agarwal, S., Maity, A., Gupta, V. K., (2015) Modeling of competitive ultrasonic assisted removal of the dyes – methylene blue and safranin-O using Fe3O4 nanoparticles. Chemical Engineering Journal, 268, 28-37.
  • Gouamid, M., Ouahrani, M. R., Bensaci, M. B., (2013) Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using date palm leaves. Energy Procedia, (36), 898-907.
  • Gupta V. K., Suhas, (2009) Application of low-cost adsorbents for dye removal – A review. Journal of Environmental Management, 90, 2313-2342.
  • Hamed, M. M., Ahmed, I. M., Metwally, S. S., (2014) Adsorptive removal of methylene blue as organic pollutant by marble dust as eco-friendly sorbent J Ind Eng Chem 20, 2370-2377.
  • Immaculate, L. A., Ouma, E. B. N., Ofomaja, A. E., (2018) Thermodynamic, kinetic and spectroscopic investigation of arsenite adsorption mechanism on pine cone-magnetite composite. Journal of Environmental Chemical Engineering, 6, 5409-5419.
  • Jian, Z., Qingwei, P., Meihong, N., Haiqiang, S., Na, L., (2013) Kinetics and equilibrium studies from the methylene blue adsorption on diatomite treated with sodium hydroxide. Applied Clay Science, 83, 12-16.
  • Jin, Y., Zeng, C., Lü, Q.-F., Yu, Y., (2019) Efficient adsorption of methylene blue and lead ions in aqueous solutions by 5-sulfosalicylic acid modified lignin. International Journal of Biological Macromolecules, 123, 50-58.
  • Kausar, A., Iqbal, M., Javeda, A., Aftab, K., Nazli, Z. H., Bhatti, H. N., Nouren, S., (2018) Adsorption Using Clay and Modified Clay: A Review. Journal of Molecular Liquids, 256, 395-407.
  • Kul, A. R., Aldemir. A., (2019) Comparison of Methylene Blue Adsorption Performance on Natural, Thermal and Acid Modified Kaolin: Isotherm, Kinetics and Thermodynamics Studies. Fresenius Environmental Bulletin, 28(6), 4475-4483.
  • Kul A. R, Koyuncu. H., (2010) Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: Kinetic, equilibrium and thermodynamic study. J Hazard Mater, 179, 332-339.
  • Kupeta, A. J. K., Naidoo, E. B., Ofomaja, A. E. (2018) Kinetics and equilibrium study of 2-nitrophenol adsorption onto polyurethane cross-linked pine cone biomass. Journal of Cleaner Production, 179, 191-209.
  • Mahmoodi, N. M., Hayati, B., Arami, M., Lan, C., (2011) Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination, 268(1-3), 117-125.
  • Martín-Lara, M. A., Blazquez, G., Calero, M., Almendros, A. I., Ronda, A., (2016) Binary biosorption of copper and lead onto pine cone shell in batch reactors and in fixed bed columns. International Journal of Mineral Processing, 148, 72-82.
  • Miyah, Y., Lahrichi, A., Idrissi, M., Khalil A., Zerrouq, F., (2018) Adsorption of methylene blue dye from aqueous solutions onto walnut shells powder: Equilibrium and kinetic studies Surfaces And Interfaces, 11 (1), 74–81.
  • Mtshatsheni, K. N. G. Ofomaja A. E., Naidoo, E. B., (2019) Synthesis and optimization of reaction variables in the preparation of pinemagnetite composite for removal of methylene blue dye. South African Journal of Chemical Engineering, 29, 33-41.
  • Ofomaja, A. E., Naidoo, E. B., Modise, S. J., (2009) Removal of copper(II) from aqueous solution by pine and base modified pine cone powder as biosorbent. J Hazard Mater, 168 (2-3), 909-17.
  • Ofomaja, A. E., Naidoo, E. B., Modise, S. J., (2010) Biosorption of copper(II) and lead(II) onto potassium hydroxide treated pine cone powder. J Environ Manage, 91(8), 1674-85.
  • Ofomaja, A. E., Naidoo, E. B., (2010) Biosorption of lead(II) onto pine cone powder: Studies on biosorption performance and process design to minimize biosorbent mass. Carbohydrate Polymers, 82(4), 1031-1042.
  • Rafatullah, M., Sulaiman, O., Hashim, R., Ahmad, A., (2010) Adsorption of methylene blue on low-cost adsorbents: a review. J Hazard Mater, 177(1-3), 70-80.
  • Rida, K., Bouraoui, S., Hadnine, S., (2013) Adsorption of methylene blue from aqueous solution by kaolin and zeolite. Applied Clay Science, 83, 99-105.
  • Salleh, M. A. M., Mahmoud, D. K., W. A. W. AbdulKarim, A. Idris, (2011) Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review. Desalination, 280(1-3), 1-13.
  • Yagub, M. T., Sen T. K., Afroze, S., Ang, H. M, (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interface Sci, 209, 172-84.
There are 33 citations in total.

Details

Primary Language English
Journal Section Articles
Authors

Adnan Aldemir 0000-0001-9884-0961

Ali Rıza Kul 0000-0001-9331-775X

Hasan Elik 0000-0003-2243-112X

Publication Date December 30, 2019
Acceptance Date December 3, 2019
Published in Issue Year 2019 Volume: 14 Issue: 4

Cite

APA Aldemir, A., Kul, A. R., & Elik, H. (2019). Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. Journal of International Environmental Application and Science, 14(4), 183-192.
AMA Aldemir A, Kul AR, Elik H. Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. J. Int. Environmental Application & Science. December 2019;14(4):183-192.
Chicago Aldemir, Adnan, Ali Rıza Kul, and Hasan Elik. “Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder”. Journal of International Environmental Application and Science 14, no. 4 (December 2019): 183-92.
EndNote Aldemir A, Kul AR, Elik H (December 1, 2019) Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. Journal of International Environmental Application and Science 14 4 183–192.
IEEE A. Aldemir, A. R. Kul, and H. Elik, “Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder”, J. Int. Environmental Application & Science, vol. 14, no. 4, pp. 183–192, 2019.
ISNAD Aldemir, Adnan et al. “Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder”. Journal of International Environmental Application and Science 14/4 (December 2019), 183-192.
JAMA Aldemir A, Kul AR, Elik H. Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. J. Int. Environmental Application & Science. 2019;14:183–192.
MLA Aldemir, Adnan et al. “Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder”. Journal of International Environmental Application and Science, vol. 14, no. 4, 2019, pp. 183-92.
Vancouver Aldemir A, Kul AR, Elik H. Isotherm, Kinetic and Thermodynamic Investigation into Methylene Blue Adsorption onto Pinecone Powder. J. Int. Environmental Application & Science. 2019;14(4):183-92.

“Journal of International Environmental Application and Science”