Research Article
BibTex RIS Cite

Utilization of Multiwalled Carbon Nanotubes as Adsorbent for Removal of Acid Violet 17 Dye: Equilibrium, Kinetics and Thermodynamic Studies

Year 2024, Volume: 45 Issue: 4, 718 - 728, 30.12.2024

Neşe Keklikcioğlu Çakmak , İlknur Şentürk

https://doi.org/10.17776/csj.1419602

Abstract

The adsorption capacity and separation efficiency of multiwalled carbon nanotube (MWCNT) were investigated for the removal of Acid Violet 17 (AV 17) dye in an aqueous solution. The effect of reaction conditions, such as contact time, AV 17 initial concentration, pH, adsorbent dosage, and temperature, on the adsorption capacity of MWCNTs was investigated. It was found that a contact time of 180 min, an adsorbent dosage of 0.8 g/L, and 100 mg/L AV 17 concentration are ideal conditions for maximum adsorption capacity (119.45 mg/g). AV 17 dye adsorption on MWCNTs followed a pseudo-second-order kinetic model (R2 = 0.9998) and the Langmuir isotherm model (R2 = 0.9813) suggesting that adsorption was the uniform and homogenous process. The maximum adsorption capacity from the Langmuir isotherm model was determined to be 322.58 mg/g. Adsorption of AV 17 dye was determined to be spontaneous and thermodynamically favorable since the values of ΔGo were negative. Positive ΔH° and ΔS° values suggest that the process is endothermic and randomness. The research results showed the MWCNTs could be used successfully to remove dye for the water treatment process.

Keywords

Multiwalled carbon nanotube Acid violet 17 Adsorption Adsorption mechanism

Ethical Statement

Etik beyan gerekmiyor.

Supporting Institution

Yok.

References

  • [1] Saleem M., Pirzada T., Qadeer R., Sorption of Some Azo-Dyes on Wool Fiber from Aqueous Solutions, Colloids Surf. A: Physicochem. Eng. Asp., 260 (1–3) (2005) 183–188.
  • [2] Saleem M., Pirzada T., Qadeer R., Sorption of Acid Violet 17 and Direct Red 80 Dyes on Cotton Fiber from Aqueous Solutions, Colloids Surf. A: Physicochem. Eng. Asp., 292 (2–3) (2007) 246–250.
  • [3] Jain S.N., Gogate P.R., Adsorptive Removal of Acid Violet 17 Dye from Wastewater Using Biosorbent Obtained from NaOH and H2SO4 Activation of Fallen Leaves of Ficus racemosa, J. Mol. Liq., 243 (2017) 132–143.
  • [4] Kodavatiganti S., Bhat A.P., Gogate P.R., Intensified Degradation of Acid Violet 7 Dye using Ultrasound Combined with Hydrogen Peroxide, Fenton, and Persulfate, Sep. Purif. Technol., 279 (2021) 119673.
  • [5] Jain S.N., Shaikh Z., Mane V.S., Vishnoi S., Mawal V.N., Patel O.R., et al., (2019) Nonlinear Regression Approach for Acid Dye Remediation Using Activated Adsorbent: Kinetic, Isotherm, Thermodynamic and Reusability Studies, Microchem J., 148 (2019) 605–615.
  • [6] Üstün-Odabaşı S., Utilizing Sustainable Hemp Biomass as an Eco-Friendly for Potentially Toxic Elements Removal from Water, Mater. Res. Express, 11 (2) (2024) 025104.
  • [7] Şentürk İ., Alzein M., Adsorption of Acid Violet 17 onto Acid-Activated Pistachio Shell: Isotherm, Kinetic and Thermodynamic Studies, Acta Chim. Slov., 67(1) (2020) 55–69.
  • [8] Jain S.N., Gogate P.R., Adsorptive Removal of Acid Violet 17 Dye from Wastewater using Biosorbent Obtained from NaOH and H2SO4 Activation of Fallen Leaves of Ficus Racemosa, J. Mol. Liq., 243 (2017) 132–143.
  • [9] Thinakaran N., Baskaralingam P., Pulikesi M., Panneerselvam P., Sivanesan S., Removal of Acid Violet 17 from Aqueous Solutions by Adsorption onto Activated Carbon Prepared from Sunflower Seed Hull, J. Hazard. Mater., 151 (2) (2008) 316–322.
  • [10] Gupta V.K., Agarwal S., Bharti A.K., Sadegh H., Adsorption Mechanism of Functionalized Multi-Walled Carbon Nanotubes for Advanced Cu (II) Removal, J. Mol. Liq., 230 (2017) 667–673.
  • [11] Al-Johani H., Salam M.A., Kinetics and Thermodynamic Study of Aniline Adsorption by Multi-Walled Carbon Nanotubes from Aqueous Solution, J. Colloid Interface Sci., 360 (2), (2011) 760–767.
  • [12] Zhou W., Zhou X., Song W., Wang C., Zhang H., Huang X., Removal of Benzohydroxamic Acid from Aqueous Solutions using Multi-Walled Carbon Nanotubes/Iron-Doped Hydroxyapatite Composites: Synthesis, Adsorption Performance, and Characteristics, J. Environ. Chem. Eng., 11 (6) (2023) 111259.
  • [13] Topal Canbaz G., Fe3O4@Granite: A Novel Magnetic Adsorbent for Dye Adsorption, Processes, 11 (9) (2023) 2681.
  • [14] Egbosiuba T.C., Egwunyenga M.C., Tijani J.O., Mustapha S., Abdulkareem A.S., Kovo A.S., et al., Activated Multi-Walled Carbon Nanotubes Decorated with Zero Valent Nickel Nanoparticles for Arsenic, Cadmium and Lead Adsorption from Wastewater in a Batch and Continuous Flow Modes, J. Hazard. Mater., 423 (2022) 126993.
  • [15] Song G., Shi Y., Wang H., Li A., Li W., Sun Y., et al., Effective Sorptive Removal of Five Cationic Dyes from Aqueous Solutions by Using Magnetic Multi-Walled Carbon Nanotubes, Water Sci. Technol., 85 (7) (2022) 1999–2014.
  • [16] Song G., Tong L., Chen S., Zhang J., Zhang Y., Wang H., et al., Facile Fabrication of Amino Functionalized Magnetic Multi-walled Carbon Nanotubes for Removal of Congo Red from Aqueous Solutions, Water Air Soil Pollut., 233 (12) (2022) 534.
  • [17] Abutaleb A., Imran M., Zouli N., Khan A.H., Hussain S., Ali M.A., et al., Fe3O4-Multiwalled Carbon Nanotubes-Bentonite as Adsorbent for Removal of Methylene Blue from Aqueous Solutions, Chemosphere, 316 (2023) 137824.
  • [18] Ho Y.S., McKay G., Pseudo-Second Order Model for Sorption Processes, Process Biochem., 34 (5) (1999) 451–465.
  • [19] Weber W.J., Morris J.C., Kinetics of Adsorption on Carbon from Solution, J. Sanit. Eng. Div., 89 (2) (1963) 31–60.
  • [20] Chien S.H., Application of Elovich Equation to the Kinetics of Phosphate Release and Sorption in Soils, Soil Sci. Soc. Am. J., 44 (2) (1980) 265–268.
  • [21] Balarak D., McKay G., Utilization of MWCNTs/Al2O3 as Adsorbent for Ciprofloxacin Removal: Equilibrium, Kinetics and Thermodynamic Studies, J. Environ. Sci. Health A Tox., Part A, 56 (3) (2021) 324–333.
  • [22] Wang J., Guo X., Adsorption Isotherm Models: Classification, Physical Meaning, Application and Solving Method, Chemosphere, 258 (2020) 127279.
  • [23] Edet U.A., Ifelebuegu A.O., Kinetics, Isotherms, and Thermodynamic Modeling of the Adsorption of Phosphates from Model Wastewater Using Recycled Brick Waste, Processes, 8 (6) (2020) 665.
  • [24] Chandrasekaran A., Patra C., Narayanasamy S., Subbiah S., Adsorptive Removal of Ciprofloxacin and Amoxicillin from Single and Binary Aqueous Systems using Acid-Activated Carbon from Prosopis juliflora, Environ. Res., 188 (2020) 109825.
  • [25] Şentürk İ., Yıldız M.R., Highly Efficient Removal from Aqueous Solution by Adsorption of Maxilon Red GRL dye using Activated Pine Sawdust, Korean J. Chem. Eng., 37 (6) (2020) 985–999.
  • [26] Şentürk İ., Effective Adsorption of Congo Red by Eco-Friendly Granite-Modified Magnetic Chitosan Nanocomposite (G@Fe3O4@CS), Biomass Conv. Bioref., (2023) https://doi.org/10.1007/s13399-023-04826-1
  • [27] Moussavi S.P., Mohammadian Fazli M., Acid Violet 17 Dye Decolorization by Multi-walled Carbon Nanotubes from Aqueous Solution, JHEHP, 1 (2) (2016) 110–117.
  • [28] Dehghani M.H., Mostofi M., Alimohammadi M., McKay G., Yetilmezsoy K., Albadarin A.B., et al., High-Performance Removal of Toxic Phenol by Single-Walled and Multi-Walled Carbon Nanotubes: Kinetics, Adsorption, Mechanism and Optimization Studies, J. Ind. Eng. Chem., 35 (2016) 63–74.
  • [29] Ahmadpour A., Eftekhari N., Ayati A., Performance of MWCNTs and a Low-Cost Adsorbent for Chromium (VI) Ion Removal, J. nanostructure chem., 4 (2014) 171–178.
  • [30] Prola L.D., Machado F.M., Bergmann C.P., de Souza F.E., Gally C.R., Lima E.C., et al., Adsorption of Direct Blue 53 Dye from Aqueous Solutions by Multi-Walled Carbon Nanotubes and Activated Carbon, J Environ Manage., 130 (2013) 166–175.
  • [31] Mishra A.K., Arockiadoss T., Ramaprabhu S., Study of Removal of Azo Dye by Functionalized Multi Walled Carbon Nanotubes, Chem. Eng. J., 162 (3) (2010) 1026–1034.
  • [32] Ahmed S.H., Rasheed E.A.A., Rasheed, L.A.A., Abdulrahim, F.R. Decolorization of Cationic Dye from Aqueous Solution by Multiwalled Carbon Nanotubes, J. Ecol. Eng., 25 (2) (2024) 72–84.
  • [33] Zhou S., Shao Y., Gao N., Deng J., Tan C., Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Triclosan onto Multi‐Walled Carbon Nanotubes, Clean - Soil Air Water, 41 (6) (2013) 539–547.
  • [34] Yao Y., Bing H., Feifei X., Xiaofeng C., Equilibrium and Kinetic Studies of Methyl Orange Adsorption On Multiwalled Carbon Nanotubes, Chem Eng J., 170 (1) (2011) 82–89.
  • [35] Abdel-Ghani N.T., El-Chaghaby G.A., Helal F.S., Individual and Competitive Adsorption of Phenol and Nickel onto Multiwalled Carbon Nanotubes, J. Adv. Res., 6 (3) (2015) 405–415.
  • [36] Alkaim A.F., Sadik Z., Mahdi D.K., Alshrefi S.M., Al-Sammarraie A.M., Alamgir F.M., et al., Preparation, Structure and Adsorption Properties of Synthesized Multiwall Carbon Nanotubes for Highly Effective Removal of Maxilon Blue Dye, Korean J. Chem. Eng., 32 (2015) 2456–2462.
  • [37] Ceroni L., Benazzato S., Pressi S., Calvillo L., Marotta E., Menna E., Enhanced Adsorption of Methylene Blue Dye on Functionalized Multi-Walled Carbon Nanotubes, Nanomaterials, 14 (6) (2024) 522.
  • [38] Wang S., Ng C.W., Wang W., Li Q., Hao Z., Synergistic and Competitive Adsorption of Organic Dyes on Multiwalled Carbon Nanotubes, Chem. Eng. J., 197 (2012) 34–40.
  • [39] Lin R., Liang Z., Yang C., Zhao Z., Cui F., Selective Adsorption of Organic Pigments on Inorganically Modified Mesoporous Biochar and Its Mechanism Based on Molecular Structure, J. Colloid Interface Sci., 573 (2020) 21–30.
  • [40] Şentürk İ., Şartlandırılmış Zeolit - Klinoptilolit Minerali ile Bakır Gideriminin Araştırılması, Karadeniz Fen Bilimleri Dergisi, 13 (1) (2023) 97–113.

Year 2024, Volume: 45 Issue: 4, 718 - 728, 30.12.2024

Neşe Keklikcioğlu Çakmak , İlknur Şentürk

https://doi.org/10.17776/csj.1419602

Abstract

References

  • [1] Saleem M., Pirzada T., Qadeer R., Sorption of Some Azo-Dyes on Wool Fiber from Aqueous Solutions, Colloids Surf. A: Physicochem. Eng. Asp., 260 (1–3) (2005) 183–188.
  • [2] Saleem M., Pirzada T., Qadeer R., Sorption of Acid Violet 17 and Direct Red 80 Dyes on Cotton Fiber from Aqueous Solutions, Colloids Surf. A: Physicochem. Eng. Asp., 292 (2–3) (2007) 246–250.
  • [3] Jain S.N., Gogate P.R., Adsorptive Removal of Acid Violet 17 Dye from Wastewater Using Biosorbent Obtained from NaOH and H2SO4 Activation of Fallen Leaves of Ficus racemosa, J. Mol. Liq., 243 (2017) 132–143.
  • [4] Kodavatiganti S., Bhat A.P., Gogate P.R., Intensified Degradation of Acid Violet 7 Dye using Ultrasound Combined with Hydrogen Peroxide, Fenton, and Persulfate, Sep. Purif. Technol., 279 (2021) 119673.
  • [5] Jain S.N., Shaikh Z., Mane V.S., Vishnoi S., Mawal V.N., Patel O.R., et al., (2019) Nonlinear Regression Approach for Acid Dye Remediation Using Activated Adsorbent: Kinetic, Isotherm, Thermodynamic and Reusability Studies, Microchem J., 148 (2019) 605–615.
  • [6] Üstün-Odabaşı S., Utilizing Sustainable Hemp Biomass as an Eco-Friendly for Potentially Toxic Elements Removal from Water, Mater. Res. Express, 11 (2) (2024) 025104.
  • [7] Şentürk İ., Alzein M., Adsorption of Acid Violet 17 onto Acid-Activated Pistachio Shell: Isotherm, Kinetic and Thermodynamic Studies, Acta Chim. Slov., 67(1) (2020) 55–69.
  • [8] Jain S.N., Gogate P.R., Adsorptive Removal of Acid Violet 17 Dye from Wastewater using Biosorbent Obtained from NaOH and H2SO4 Activation of Fallen Leaves of Ficus Racemosa, J. Mol. Liq., 243 (2017) 132–143.
  • [9] Thinakaran N., Baskaralingam P., Pulikesi M., Panneerselvam P., Sivanesan S., Removal of Acid Violet 17 from Aqueous Solutions by Adsorption onto Activated Carbon Prepared from Sunflower Seed Hull, J. Hazard. Mater., 151 (2) (2008) 316–322.
  • [10] Gupta V.K., Agarwal S., Bharti A.K., Sadegh H., Adsorption Mechanism of Functionalized Multi-Walled Carbon Nanotubes for Advanced Cu (II) Removal, J. Mol. Liq., 230 (2017) 667–673.
  • [11] Al-Johani H., Salam M.A., Kinetics and Thermodynamic Study of Aniline Adsorption by Multi-Walled Carbon Nanotubes from Aqueous Solution, J. Colloid Interface Sci., 360 (2), (2011) 760–767.
  • [12] Zhou W., Zhou X., Song W., Wang C., Zhang H., Huang X., Removal of Benzohydroxamic Acid from Aqueous Solutions using Multi-Walled Carbon Nanotubes/Iron-Doped Hydroxyapatite Composites: Synthesis, Adsorption Performance, and Characteristics, J. Environ. Chem. Eng., 11 (6) (2023) 111259.
  • [13] Topal Canbaz G., Fe3O4@Granite: A Novel Magnetic Adsorbent for Dye Adsorption, Processes, 11 (9) (2023) 2681.
  • [14] Egbosiuba T.C., Egwunyenga M.C., Tijani J.O., Mustapha S., Abdulkareem A.S., Kovo A.S., et al., Activated Multi-Walled Carbon Nanotubes Decorated with Zero Valent Nickel Nanoparticles for Arsenic, Cadmium and Lead Adsorption from Wastewater in a Batch and Continuous Flow Modes, J. Hazard. Mater., 423 (2022) 126993.
  • [15] Song G., Shi Y., Wang H., Li A., Li W., Sun Y., et al., Effective Sorptive Removal of Five Cationic Dyes from Aqueous Solutions by Using Magnetic Multi-Walled Carbon Nanotubes, Water Sci. Technol., 85 (7) (2022) 1999–2014.
  • [16] Song G., Tong L., Chen S., Zhang J., Zhang Y., Wang H., et al., Facile Fabrication of Amino Functionalized Magnetic Multi-walled Carbon Nanotubes for Removal of Congo Red from Aqueous Solutions, Water Air Soil Pollut., 233 (12) (2022) 534.
  • [17] Abutaleb A., Imran M., Zouli N., Khan A.H., Hussain S., Ali M.A., et al., Fe3O4-Multiwalled Carbon Nanotubes-Bentonite as Adsorbent for Removal of Methylene Blue from Aqueous Solutions, Chemosphere, 316 (2023) 137824.
  • [18] Ho Y.S., McKay G., Pseudo-Second Order Model for Sorption Processes, Process Biochem., 34 (5) (1999) 451–465.
  • [19] Weber W.J., Morris J.C., Kinetics of Adsorption on Carbon from Solution, J. Sanit. Eng. Div., 89 (2) (1963) 31–60.
  • [20] Chien S.H., Application of Elovich Equation to the Kinetics of Phosphate Release and Sorption in Soils, Soil Sci. Soc. Am. J., 44 (2) (1980) 265–268.
  • [21] Balarak D., McKay G., Utilization of MWCNTs/Al2O3 as Adsorbent for Ciprofloxacin Removal: Equilibrium, Kinetics and Thermodynamic Studies, J. Environ. Sci. Health A Tox., Part A, 56 (3) (2021) 324–333.
  • [22] Wang J., Guo X., Adsorption Isotherm Models: Classification, Physical Meaning, Application and Solving Method, Chemosphere, 258 (2020) 127279.
  • [23] Edet U.A., Ifelebuegu A.O., Kinetics, Isotherms, and Thermodynamic Modeling of the Adsorption of Phosphates from Model Wastewater Using Recycled Brick Waste, Processes, 8 (6) (2020) 665.
  • [24] Chandrasekaran A., Patra C., Narayanasamy S., Subbiah S., Adsorptive Removal of Ciprofloxacin and Amoxicillin from Single and Binary Aqueous Systems using Acid-Activated Carbon from Prosopis juliflora, Environ. Res., 188 (2020) 109825.
  • [25] Şentürk İ., Yıldız M.R., Highly Efficient Removal from Aqueous Solution by Adsorption of Maxilon Red GRL dye using Activated Pine Sawdust, Korean J. Chem. Eng., 37 (6) (2020) 985–999.
  • [26] Şentürk İ., Effective Adsorption of Congo Red by Eco-Friendly Granite-Modified Magnetic Chitosan Nanocomposite (G@Fe3O4@CS), Biomass Conv. Bioref., (2023) https://doi.org/10.1007/s13399-023-04826-1
  • [27] Moussavi S.P., Mohammadian Fazli M., Acid Violet 17 Dye Decolorization by Multi-walled Carbon Nanotubes from Aqueous Solution, JHEHP, 1 (2) (2016) 110–117.
  • [28] Dehghani M.H., Mostofi M., Alimohammadi M., McKay G., Yetilmezsoy K., Albadarin A.B., et al., High-Performance Removal of Toxic Phenol by Single-Walled and Multi-Walled Carbon Nanotubes: Kinetics, Adsorption, Mechanism and Optimization Studies, J. Ind. Eng. Chem., 35 (2016) 63–74.
  • [29] Ahmadpour A., Eftekhari N., Ayati A., Performance of MWCNTs and a Low-Cost Adsorbent for Chromium (VI) Ion Removal, J. nanostructure chem., 4 (2014) 171–178.
  • [30] Prola L.D., Machado F.M., Bergmann C.P., de Souza F.E., Gally C.R., Lima E.C., et al., Adsorption of Direct Blue 53 Dye from Aqueous Solutions by Multi-Walled Carbon Nanotubes and Activated Carbon, J Environ Manage., 130 (2013) 166–175.
  • [31] Mishra A.K., Arockiadoss T., Ramaprabhu S., Study of Removal of Azo Dye by Functionalized Multi Walled Carbon Nanotubes, Chem. Eng. J., 162 (3) (2010) 1026–1034.
  • [32] Ahmed S.H., Rasheed E.A.A., Rasheed, L.A.A., Abdulrahim, F.R. Decolorization of Cationic Dye from Aqueous Solution by Multiwalled Carbon Nanotubes, J. Ecol. Eng., 25 (2) (2024) 72–84.
  • [33] Zhou S., Shao Y., Gao N., Deng J., Tan C., Equilibrium, Kinetic, and Thermodynamic Studies on the Adsorption of Triclosan onto Multi‐Walled Carbon Nanotubes, Clean - Soil Air Water, 41 (6) (2013) 539–547.
  • [34] Yao Y., Bing H., Feifei X., Xiaofeng C., Equilibrium and Kinetic Studies of Methyl Orange Adsorption On Multiwalled Carbon Nanotubes, Chem Eng J., 170 (1) (2011) 82–89.
  • [35] Abdel-Ghani N.T., El-Chaghaby G.A., Helal F.S., Individual and Competitive Adsorption of Phenol and Nickel onto Multiwalled Carbon Nanotubes, J. Adv. Res., 6 (3) (2015) 405–415.
  • [36] Alkaim A.F., Sadik Z., Mahdi D.K., Alshrefi S.M., Al-Sammarraie A.M., Alamgir F.M., et al., Preparation, Structure and Adsorption Properties of Synthesized Multiwall Carbon Nanotubes for Highly Effective Removal of Maxilon Blue Dye, Korean J. Chem. Eng., 32 (2015) 2456–2462.
  • [37] Ceroni L., Benazzato S., Pressi S., Calvillo L., Marotta E., Menna E., Enhanced Adsorption of Methylene Blue Dye on Functionalized Multi-Walled Carbon Nanotubes, Nanomaterials, 14 (6) (2024) 522.
  • [38] Wang S., Ng C.W., Wang W., Li Q., Hao Z., Synergistic and Competitive Adsorption of Organic Dyes on Multiwalled Carbon Nanotubes, Chem. Eng. J., 197 (2012) 34–40.
  • [39] Lin R., Liang Z., Yang C., Zhao Z., Cui F., Selective Adsorption of Organic Pigments on Inorganically Modified Mesoporous Biochar and Its Mechanism Based on Molecular Structure, J. Colloid Interface Sci., 573 (2020) 21–30.
  • [40] Şentürk İ., Şartlandırılmış Zeolit - Klinoptilolit Minerali ile Bakır Gideriminin Araştırılması, Karadeniz Fen Bilimleri Dergisi, 13 (1) (2023) 97–113.
There are 40 citations in total.

Details

Primary Language English
Subjects Chemical Engineering (Other), Composite and Hybrid Materials
Journal Section Natural Sciences
Authors

Neşe Keklikcioğlu Çakmak 0000-0002-8634-9232

İlknur Şentürk 0000-0002-8217-2281

Publication Date December 30, 2024
Submission Date January 14, 2024
Acceptance Date September 7, 2024
Published in Issue Year 2024Volume: 45 Issue: 4

Cite

APA Keklikcioğlu Çakmak, N., & Şentürk, İ. (2024). Utilization of Multiwalled Carbon Nanotubes as Adsorbent for Removal of Acid Violet 17 Dye: Equilibrium, Kinetics and Thermodynamic Studies. Cumhuriyet Science Journal, 45(4), 718-728. https://doi.org/10.17776/csj.1419602
 Download Cover Image