Research Article
PDF EndNote BibTex RIS Cite

Piranha ve Silan Modifikasyonlarının Bor Nitrür Nanosheets (BNNSs) İnce Film Oluşumu Üzerine Etkisi

Year 2019, Volume 40, Issue 2, 424 - 432, 30.06.2019
https://doi.org/10.17776/csj.521889

Abstract

Bu çalışmada, iki faz arasındaki (cam alt tabaka ve BNNSs filmi) yapışmanın arttırılması amaçlanmıştır. Yüzey iyileştirmesi TEOS silan grubu ve piranha çözeltisi ile sağlanmıştır. Cam yüzeylerin piranha çözeltisinde tutunma süreleri ve silan çözeltisinin farklı oranlarının cam yüzeyine yapışması incelenmiştir. Yüzey karakterizasyonu Fourier Transform Infrared Spektrofotometre (FT-IR) ile yapılmıştır. Yüzey morfolojisini, ince filmlerin kalınlığını ve bor nitrür nanosheetlerin yapısını karakterize etmek için Taramalı Elektron Mikroskobu (SEM) görüntüleri alınmıştır. Eksfoliasyon işleminden sonra bor nitrür nanosheetlerin verimliliğini belirlemek için UV görünür bölge spektrofotometresi kullanılmıştır. İnce filmlerin yüzey pürüzlülüğünü belirlemek için yüzey pürüzlülük cihazı (Time TR200) kullanılmıştır. Sonuçlara göre piranha ve silan çözeltilerinin cam yüzeyini yapışma için geliştirdiği görülmüştür. SEM görüntüleri silanın cam yüzeyinde kaplandığını ve kaplama malzemesinin silan üzerinde tutunduğunu göstermiştir. Silan yüklemesinin fazla olması yapıda bozulmalara neden olmuştur. Eksfoliasyon sonrası farklı santrifüjleme hızları için bor nitrür verimi %54,1 ve %34,1 olarak hesaplanmıştır.

References

  • Chitvoranund N., Jiemsirilers S., Kashima D.P., Effects of surface treatments on adhesion of silver film on glass substrate fabricated by electroless plating, J. Aust. Ceram. Soc., 49 (2013) 62-69.
  • Muanpho K., Praserthdam P., Pavarajarn V., Surface Modification for fabrication of gold nanoparticles thin film on glass substrate, In: 4th Thailand Materials Science and Technology Conference; 31 March-1 April (2006) Bangkok, Thailand.
  • Nguyen C.V., Bartali R., Crema L., Speranza G., Effect of glass surface treatments on the deposition of highlytransparent reduced graphene oxide films by dropcasting method, Colloid Surface A, 498 (2016) 231-238.
  • Wang Y.Z. and Awadelkarim O.O., The Effects of Glass-Substrate’s Surface-Treatment on the Characteristics of N-Channel Polycrystalline Silicon Thin Film Transistors, J. Electron. Mater., 27 (1998) 77-80.
  • Pacaphol K. and Aht-Ong D., The influences of silanes on interfacial adhesion and surface properties of nanocellulose film coating on glass and aluminum substrates, Surf&Coat. Tech., 320 (2017) 70-81.
  • Ahmad F., Jamil M., Jeon Y.J., Alteration of glass surface via polyvinyl butyral (PVB) layer for reverse mode polymer dispersed liquid crystal (R-PDLC) display, Phase Transit., 90 (2017) 873-881.
  • Wang Z., Tang Z., Xue Q., Huang Y., Huang Y., Zhu M., Pei Z., Li H., Jiang H., Fu C., Zhi C., Fabrication of Boron Nitride Nanosheets by Exfoliation, Chem. Rec. 16 (2016) 1204- 1215.
  • Li X., Hao X., Zhao M., Wu Y., Yang J., Tian Y., Qian G., Exfoliation of hexagonal boron nitride by molten hydroxides, Adv. Mater., 25 (2013) 2200-2204.
  • Wang Y., Shi Z., Yin J., Boron nitride nanosheets: large-scale exfoliation in methanesulfonic acid and their composites with polybenzimidazole, J. Mater. Chem., 21 (2011) 11371-11377.
  • Zhi B.C., Bando Y., Tang C., Kuwahara H., Golberg D., Large-Scale Fabrication of Boron Nitride Nanosheets and Their Utilization in Polymeric Composites with Improved Thermal and Mechanical Properties, Adv. Mater., 21 (2009) 2889-2893.
  • Liu J., Kutty R.G., Zheng Q., Eswariah V., Sreejith S., Liu Z., Hexagonal Boron Nitride Nanosheets as High-Performance Binder-Free Fire-Resistant Wood Coatings, Small, 13 (2016) 1602456.
  • Dvir H. and Gottlieb M., Effect of Silane Sizing on Polymer-Glass Adhesion, Am. Phys. Soc., (2007) APS March Meeting; March 5-9,2007; Denver, Colorado.
  • Cecchin D., Farina A.P., Vitti R.P., Moraes R.R., Bacchi A., Spazzin A.O., Acid Etching and Surface Coating of Glass-Fiber Posts: Bond Strength and Interface Analysis, Braz. Dent. J., 27 (2016) 228-233.
  • Rubio F., Rubio J., Oteo J.L., A FT-IR Study of the Hydrolysis of Tetraethylortho silicate(TEOS), Spectrosc. Lett., 31 (2013) 199-219.
  • Marsh K.L., Souliman M., Kaner R.B., Co-solvent exfoliation and suspension of hexagonal boron nitride, Chem. Commun., 51 (2015) 187-190.
  • Durge R., Kshirsagar R.V., Tambe P., Effect of sonication energy on the yield of graphene nanosheets by liquid-phase exfoliation of graphite, Procedia Engineer, 97 (2014) 1457-1465.
  • Smielak B. and Klimek L., Effect of hydrofluoric acid concentration and etching duration on select surface roughness parameters for zirconia, J. Prosthet. Dent., 113 (2015) 596-602.
  • Affatigato M., Osborne D.H., Haglund R.F., Effect of Surface Roughness on the Acid Etching of Amorphous Silica, J. Am. Ceram. Soc., 79 (1996) 688-694.
  • Zogheib L.V., Della Bona A., Kimpara E.T., Mccabe J.F., Effect of Hydrofluoric Acid Etching Duration on the Roughness and Flexural Strength of a Lithium Disilicate-Based Glass Ceramic, Braz. Dent. J., 22 (2011) 45-50.

The Effect of Piranha and Silane Modifications on Boron Nitride Nanosheets (BNNSs) Thin Film Formation

Year 2019, Volume 40, Issue 2, 424 - 432, 30.06.2019
https://doi.org/10.17776/csj.521889

Abstract

In this study, the aim was to increase the adhesion between the two phases (glass substrate and BNNSs film). Surface treatment was provided by TEOS silane group and piranha solution. The retention times of the glass surfaces in the piranha solution and the adherence of different ratios of the silane solution to the glass surface were investigated. Surface characterization was carried out by Fourier Transform Infrared Spectrophotometer (FT-IR). Scanning Electron Microscopy (SEM) images were taken to characterize the surface morphology, the thickness of the thin films and the structure of boron nitride nanosheets. UV visible spectrophotometer was used to determine the efficiency of boron nitride nanosheets after the exfoliation process. Surface roughness tester (Time TR200) was used to determine surface roughness of the thin films. According to the results, it was observed that the piranha and silane solutions improved the adhesion of the glass surface. SEM images showed that the silane was coated on the glass surface and the coating material was retained on the silane. Excess silane loading caused the structure to deteriorate. Boron nitride yield was calculated and found to be 54.1% and 34.1% for different centrifugation rates after exfoliation.

References

  • Chitvoranund N., Jiemsirilers S., Kashima D.P., Effects of surface treatments on adhesion of silver film on glass substrate fabricated by electroless plating, J. Aust. Ceram. Soc., 49 (2013) 62-69.
  • Muanpho K., Praserthdam P., Pavarajarn V., Surface Modification for fabrication of gold nanoparticles thin film on glass substrate, In: 4th Thailand Materials Science and Technology Conference; 31 March-1 April (2006) Bangkok, Thailand.
  • Nguyen C.V., Bartali R., Crema L., Speranza G., Effect of glass surface treatments on the deposition of highlytransparent reduced graphene oxide films by dropcasting method, Colloid Surface A, 498 (2016) 231-238.
  • Wang Y.Z. and Awadelkarim O.O., The Effects of Glass-Substrate’s Surface-Treatment on the Characteristics of N-Channel Polycrystalline Silicon Thin Film Transistors, J. Electron. Mater., 27 (1998) 77-80.
  • Pacaphol K. and Aht-Ong D., The influences of silanes on interfacial adhesion and surface properties of nanocellulose film coating on glass and aluminum substrates, Surf&Coat. Tech., 320 (2017) 70-81.
  • Ahmad F., Jamil M., Jeon Y.J., Alteration of glass surface via polyvinyl butyral (PVB) layer for reverse mode polymer dispersed liquid crystal (R-PDLC) display, Phase Transit., 90 (2017) 873-881.
  • Wang Z., Tang Z., Xue Q., Huang Y., Huang Y., Zhu M., Pei Z., Li H., Jiang H., Fu C., Zhi C., Fabrication of Boron Nitride Nanosheets by Exfoliation, Chem. Rec. 16 (2016) 1204- 1215.
  • Li X., Hao X., Zhao M., Wu Y., Yang J., Tian Y., Qian G., Exfoliation of hexagonal boron nitride by molten hydroxides, Adv. Mater., 25 (2013) 2200-2204.
  • Wang Y., Shi Z., Yin J., Boron nitride nanosheets: large-scale exfoliation in methanesulfonic acid and their composites with polybenzimidazole, J. Mater. Chem., 21 (2011) 11371-11377.
  • Zhi B.C., Bando Y., Tang C., Kuwahara H., Golberg D., Large-Scale Fabrication of Boron Nitride Nanosheets and Their Utilization in Polymeric Composites with Improved Thermal and Mechanical Properties, Adv. Mater., 21 (2009) 2889-2893.
  • Liu J., Kutty R.G., Zheng Q., Eswariah V., Sreejith S., Liu Z., Hexagonal Boron Nitride Nanosheets as High-Performance Binder-Free Fire-Resistant Wood Coatings, Small, 13 (2016) 1602456.
  • Dvir H. and Gottlieb M., Effect of Silane Sizing on Polymer-Glass Adhesion, Am. Phys. Soc., (2007) APS March Meeting; March 5-9,2007; Denver, Colorado.
  • Cecchin D., Farina A.P., Vitti R.P., Moraes R.R., Bacchi A., Spazzin A.O., Acid Etching and Surface Coating of Glass-Fiber Posts: Bond Strength and Interface Analysis, Braz. Dent. J., 27 (2016) 228-233.
  • Rubio F., Rubio J., Oteo J.L., A FT-IR Study of the Hydrolysis of Tetraethylortho silicate(TEOS), Spectrosc. Lett., 31 (2013) 199-219.
  • Marsh K.L., Souliman M., Kaner R.B., Co-solvent exfoliation and suspension of hexagonal boron nitride, Chem. Commun., 51 (2015) 187-190.
  • Durge R., Kshirsagar R.V., Tambe P., Effect of sonication energy on the yield of graphene nanosheets by liquid-phase exfoliation of graphite, Procedia Engineer, 97 (2014) 1457-1465.
  • Smielak B. and Klimek L., Effect of hydrofluoric acid concentration and etching duration on select surface roughness parameters for zirconia, J. Prosthet. Dent., 113 (2015) 596-602.
  • Affatigato M., Osborne D.H., Haglund R.F., Effect of Surface Roughness on the Acid Etching of Amorphous Silica, J. Am. Ceram. Soc., 79 (1996) 688-694.
  • Zogheib L.V., Della Bona A., Kimpara E.T., Mccabe J.F., Effect of Hydrofluoric Acid Etching Duration on the Roughness and Flexural Strength of a Lithium Disilicate-Based Glass Ceramic, Braz. Dent. J., 22 (2011) 45-50.

Details

Primary Language English
Subjects Basic Sciences
Journal Section Natural Sciences
Authors

Duygu KURU>
BİLECİK ŞEYH EDEBALİ ÜNİVERSİTESİ
0000-0002-9727-5785
Türkiye


Alev AKPINAR BORAZAN> (Primary Author)
BİLECİK ŞEYH EDEBALİ ÜNİVERSİTESİ
0000-0002-3815-2101
Türkiye


Nuran AY>
ESKİŞEHİR TEKNİK ÜNİVERSİTESİ
0000-0002-2228-9904
Türkiye

Publication Date June 30, 2019
Submission Date February 4, 2019
Acceptance Date April 20, 2019
Published in Issue Year 2019, Volume 40, Issue 2

Cite

APA Kuru, D. , Akpınar Borazan, A. & Ay, N. (2019). The Effect of Piranha and Silane Modifications on Boron Nitride Nanosheets (BNNSs) Thin Film Formation . Cumhuriyet Science Journal , 40 (2) , 424-432 . DOI: 10.17776/csj.521889