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An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution

Year 2021, Volume: 7 Issue: 2, 119 - 130, 20.11.2021
https://doi.org/10.26672/anatolianbryology.984722

Abstract

In this study, the corrosion inhibition effect of Plagiochila porelloides (Torr. ex Nees) Lindenb. extract, a Marchantiophyta species, on mild steel in hydrochloric acid solution at 298 K was investigated for the first time by applying electrochemical impedance spectroscopy (EIS), linear polarization (LPR) and potentiodynamic polarization techniques. Experiments were performed by immersing mild steel electrodes in acidic solutions containing different concentrations of Plagiochila porelloides extract for 1 hour before each electrochemical measurement to equilibrate with the aggressive solution. Liverwort extract showed a strong inhibitory effect as a result of 1 hour electrochemical experiments, and as the extract concentration increased, the protective effect of mild steel in acidic solutions raised. In addition, the surface images of the electrodes in 1.0 M HCl solutions with and without liverwort extract after 1-hour exposure were examined by an optical microscope and it was shown that the metal surface in the inhibited extract solution had a smoother appearance compared to the uninhibited metal surface. Electrochemical findings and surface images support each other.

Thanks

The author would like to thank, in the process of providing and identifying the plant material to Prof. Dr. Tülay Ezer, and also to Prof. Dr. Osman Seyyar for photographed of the plant material.

References

  • Abu-Baker A.N. Khalil L.A. Al-Gonmeen T. 2021. A multi-analytical exploration of the chemical composition, microstructural properties and corrosion inhibiting treatment for an archaeological brass censer from Umm Zuwaytinah, Amman. Nucl. Instrum. Methods Phys. Res. B. 502: 73-79.
  • Alrebh A. Rammal M.B. Omanovic S. 2021. A pyridine derivative 2-(2-Methylaminoethyl)pyridine (MAEP) as a ‘green’ corrosion inhibitor for low-carbon steel in hydrochloric acid media. J. Mol. Struct. 1238:8, 130333.
  • Cansu T.B. Yaylı B. Özdemir T. Batan N. Alpay-Karaoğlu Ş. Yaylı N. 2013. Antimicrobial activity and chemical composition of the essential oils of mosses (Hylocomium splendens (Hedw.) Schimp. and Leucodon sciuroides (Hedw.) Schwägr.) growing in Turkey. Turk. J. Chem. 37:2, 213-219.
  • Cansu T.B. Özdemir T. Batan N. Yaylı B. Alpay-Karaoğlu Ş. Yaylı N. 2014. Essential Oil Analysis and Antimicrobial Activity of Neckera complanata (Hedw.) Huebener and Neckera crispa Hedw. (Neckeraceae) Grown in Turkey. Asian J. Chem. 26:7, 2005-2008.
  • Charitha B.P. Rao P. 2018. Pullulan as a potent green inhibitor for corrosion mitigation of aluminum composite: Electrochemical and surface studies. Int. J. Biol. Macromol. 112: 461–472.
  • Chaubey N. Savita. Qurashi A. Chauhan D.S. Quraishi M.A. 2021. Frontiers and advances in green and sustainable inhibitors for corrosion applications: A critical review. J. Mol. Liq. 321: 114385.
  • El Tamany El-S.H. Elsaeed S.M. Ashour H. Zaki E.G. El Nagy H.A. 2018. Novel acrylamide ionic liquids as anti-corrosion for X-65 steel dissolution in acid medium: Adsorption, hydrogen evolution and mechanism. J. Mol. Struct. 1168: 106-114.
  • Feng Y. He J. Zhan Y. An J. Tan B. 2021. Insight into the anti-corrosion mechanism Veratrum root extract as a green corrosion inhibitör. J. Mol. Liq. 334: 116110.
  • Guruprasad A.M. Sachin H.P. 2021. Novel cost-effective aqueous Amorphophallus paeoniifolius leaves extract as a green corrosion inhibitor for mild steel corrosion in hydrochloric acid medium: A detailed experimental and surface characterization studies. Chem. Data Coll. 34: 100734.
  • Huang Y. Xiao D. Burton-Freeman B.M. Edirisinghe I. 2016. Chemical changes of bioactive phytochemicals during thermal processing. In: Reference Module in Food Science. Elsevier.
  • Kumar H. Yadav V. 2020. Musa acuminata (Green corrosion inhibitor) as anti-pit and anti-cracking agent for mild steel in 5M hydrochloric acid solution. Chemical Data Collections. 29: 100500.
  • Li H. Qiang Y. Zhao W. Zhang S. 2021. A green Brassica oleracea L extract as a novel corrosion inhibitor for Q235 steel in two typical acid media. Colloids Surf. A Physicochem. Eng. Asp. 616: 126077.
  • Ma L. Lu W. Yang D. Shen J. Gao Z. Zhang S. Liao Q. 2021. Dithiocarbamate modified glucose as a novel eco-friendly corrosion inhibitor for copper in sodium chloride media. Sustain. Chem. Pharm. 22: 100488.
  • Mao T. Huang H. Liu D. Shang X. Wang W. Wang L. 2021. Novel cationic Gemini ester surfactant as an efficient and eco-friendly corrosion inhibitor for carbon steel in HCl solution. J. Mol. Liq. 339: 117174.
  • Nam N.D. Hien P.V. Hoai N.T. Thu V.T.H. 2018. A study on the mixed corrosion inhibitor with a dominant cathodic inhibitor for mild steel in aqueous chloride solution. J. Taiwan Inst. Chem. Eng. 91: 556-569.
  • Özkır D. Kayakırılmaz K. Bayol E. Gürten A.A. Kandemirli F. 2012. The inhibition effect of Azure A on mild steel in 1M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects. Corrosion Science. 56: 143–152.
  • Özkır D. Çifcibaşı Ö. 2017. The Investigation of the Adsorption of a Schiff Base Derivated from 2,5-Dichloroaniline as an Inhibitor on Mild Steel Corrosion in Acidic Medium by Electrochemical Methods. Engineering Sciences. 12:2, 97-107.
  • Özkır D. 2018. A new example of mild steel corrosion inhibitors synthesized from Chloroaniline: 2-[(2,5- dichlorophenylimino) methyl] phenol. OHU J. Eng. Sci. 7:2, 993-1003.
  • Özkır D. 2019a. A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques. J. Electrochem. Sci. Technol. 10:1, 37-54.
  • Özkır D. 2019b. The Electrochemical Variation of a Kind of Protein Staining and Food Dye as a New Corrosion Inhibitor on Mild Steel in Acidic Medium. International Journal of Electrochemistry. 2019: 1-11.
  • Özkır D. 2019c. A Corrosion Study: Use of Thionine dye having structurally metachromatic influence. Int. J. Chem. Technol. 3:1, 17-25.
  • Özkır D. Ezer T. 2020. A New Inhibitor Approach to the Corrosion of Mild Steel in Acidic Solution with Long-Term Impedance Tests: A New Application Area for Hypnum cupressiforme (Bryophyta). Anatolian Bryology. 6:2, 119-128.
  • Özkır D. Kayakırılmaz K. 2020. The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel. J. Electrochem. Sci. Technol. 11:3, 257-272.
  • Paton J.A. 1999. The Liverworts flora of the British Isles. Harley Press, 626 p. England.
  • Rodrigues F.A.d.S. Gonçalves Y.M.H. Horta B.A.C. Santos I.d.S. Silva B.V. D’Elia E. 2021. Experimental and theoretical studies of isonitrosoacetanilides derivatives as corrosion inhibitors for mild steel in 1 mol L−1 HCl. J. Mol. Struct. 1245: 131-256.
  • Salmasifar A. Edraki M. Alibakhshi E. Ramezanzadeh B. Bahlakeh G. 2021. Combined electrochemical/surface investigations and computer modeling of the aquatic Artichoke extract molecules corrosion inhibition properties on the mild steel surface immersed in the acidic medium. J. Mol. Liq. 327: 114856.
  • Smith A.J.E. 1996. The liverworts of Britain and Ireland, Cambridge University Press. 362 p. Cambridge.
  • Sürme Y. Gürten A.A. 2009. Role of polyethylene glycol tert-octylphenyl ether on corrosion behaviour of mild steel in acidic solution. Corros. Eng. Sci. Techn. 44:4, 304–311.
  • Tosun G. Yayli B. Özdemir T. Batan N. Bozdeveci A. Yayli N. 2015. Volatiles and Antimicrobial Activity of the Essential Oils of the Mosses Pseudoscleropodium purum, Eurhynchium striatum, and Eurhynchium angustirete Grown in Turkey. Rec. Nat. Prod. 9: 237-242.
  • Zhang X. Li W. Yu G. Zuo X. Luo W. Zhang J. Tan B. Fu A. Zhang S. 2020. Evaluation of Idesia polycarpa Maxim fruits extract as a natural green corrosion inhibitor for copper in 0.5 M sulfuric acid solution. J. Mol. Liq. 318: 114080.
  • Zohdy K.M. El-Sherif R.M. Ramkumar S. El-Shamy A.M. 2021. Quantum and electrochemical studies of the hydrogen evolution findings in corrosion reactions of mild steel in acidic medium. Upstream Oil and Gas Technology. 6: 100025.

Asidik Çözeltide Yumuşak Çelik için Çevresel Olarak Sürdürülebilir Yeni Bir Yeşil Korozyon İnhibitörü Olarak Plagiochila porelloides (Marchantiophyta)’e Genel Bir Bakış

Year 2021, Volume: 7 Issue: 2, 119 - 130, 20.11.2021
https://doi.org/10.26672/anatolianbryology.984722

Abstract

Bir Marchantiophyta türü olan Plagiochila porelloides (Torr. ex Nees) Lindenb. ekstraktının 298 K’de hidroklorik asit çözeltisindeki yumuşak çeliğin korozyonu üzerine inhibisyon etkisi, ilk kez bu çalışmada elektrokimyasal impedans spektroskopisi (EIS), lineer polarizasyon (LPR) ve potansiyodinamik polarizasyon yöntemleri uygulanarak araştırılmıştır. Deneyler, her elektrokimyasal ölçümden önce yumuşak çelik elektrotların agresif çözelti ile dengeye gelmesi için 1 saat boyunca farklı konsantrasyonlarda Plagiochila porelloides özütü içeren asidik çözeltilere daldırılmasıyla gerçekleştirilmiştir. Ciğerotu özütü 1 saatlik elektrokimyasal deneyler sonucunda, güçlü bir inhibitör etki göstererek özüt derişimi arttıkça, asidik çözeltilerdeki yumuşak çeliği koruma etkisi artmıştır. Ayrıca, 1 saatlik daldırma süresi sonrasında inhibitörlü ve inhibitörsüz 1,0 M HCl çözeltilerine daldırılan elektrotların yüzey morfolojileri optik mikroskopta incelenmiş ve inhibitörlü çözeltideki metal yüzeyinin inhibitörsüz olan metal yüzeyine göre daha düzgün bir görüntüye sahip olduğu gösterilmiştir. Elektrokimyasal bulgular ve yüzey görüntüleri birbirini destekler niteliktedir.

References

  • Abu-Baker A.N. Khalil L.A. Al-Gonmeen T. 2021. A multi-analytical exploration of the chemical composition, microstructural properties and corrosion inhibiting treatment for an archaeological brass censer from Umm Zuwaytinah, Amman. Nucl. Instrum. Methods Phys. Res. B. 502: 73-79.
  • Alrebh A. Rammal M.B. Omanovic S. 2021. A pyridine derivative 2-(2-Methylaminoethyl)pyridine (MAEP) as a ‘green’ corrosion inhibitor for low-carbon steel in hydrochloric acid media. J. Mol. Struct. 1238:8, 130333.
  • Cansu T.B. Yaylı B. Özdemir T. Batan N. Alpay-Karaoğlu Ş. Yaylı N. 2013. Antimicrobial activity and chemical composition of the essential oils of mosses (Hylocomium splendens (Hedw.) Schimp. and Leucodon sciuroides (Hedw.) Schwägr.) growing in Turkey. Turk. J. Chem. 37:2, 213-219.
  • Cansu T.B. Özdemir T. Batan N. Yaylı B. Alpay-Karaoğlu Ş. Yaylı N. 2014. Essential Oil Analysis and Antimicrobial Activity of Neckera complanata (Hedw.) Huebener and Neckera crispa Hedw. (Neckeraceae) Grown in Turkey. Asian J. Chem. 26:7, 2005-2008.
  • Charitha B.P. Rao P. 2018. Pullulan as a potent green inhibitor for corrosion mitigation of aluminum composite: Electrochemical and surface studies. Int. J. Biol. Macromol. 112: 461–472.
  • Chaubey N. Savita. Qurashi A. Chauhan D.S. Quraishi M.A. 2021. Frontiers and advances in green and sustainable inhibitors for corrosion applications: A critical review. J. Mol. Liq. 321: 114385.
  • El Tamany El-S.H. Elsaeed S.M. Ashour H. Zaki E.G. El Nagy H.A. 2018. Novel acrylamide ionic liquids as anti-corrosion for X-65 steel dissolution in acid medium: Adsorption, hydrogen evolution and mechanism. J. Mol. Struct. 1168: 106-114.
  • Feng Y. He J. Zhan Y. An J. Tan B. 2021. Insight into the anti-corrosion mechanism Veratrum root extract as a green corrosion inhibitör. J. Mol. Liq. 334: 116110.
  • Guruprasad A.M. Sachin H.P. 2021. Novel cost-effective aqueous Amorphophallus paeoniifolius leaves extract as a green corrosion inhibitor for mild steel corrosion in hydrochloric acid medium: A detailed experimental and surface characterization studies. Chem. Data Coll. 34: 100734.
  • Huang Y. Xiao D. Burton-Freeman B.M. Edirisinghe I. 2016. Chemical changes of bioactive phytochemicals during thermal processing. In: Reference Module in Food Science. Elsevier.
  • Kumar H. Yadav V. 2020. Musa acuminata (Green corrosion inhibitor) as anti-pit and anti-cracking agent for mild steel in 5M hydrochloric acid solution. Chemical Data Collections. 29: 100500.
  • Li H. Qiang Y. Zhao W. Zhang S. 2021. A green Brassica oleracea L extract as a novel corrosion inhibitor for Q235 steel in two typical acid media. Colloids Surf. A Physicochem. Eng. Asp. 616: 126077.
  • Ma L. Lu W. Yang D. Shen J. Gao Z. Zhang S. Liao Q. 2021. Dithiocarbamate modified glucose as a novel eco-friendly corrosion inhibitor for copper in sodium chloride media. Sustain. Chem. Pharm. 22: 100488.
  • Mao T. Huang H. Liu D. Shang X. Wang W. Wang L. 2021. Novel cationic Gemini ester surfactant as an efficient and eco-friendly corrosion inhibitor for carbon steel in HCl solution. J. Mol. Liq. 339: 117174.
  • Nam N.D. Hien P.V. Hoai N.T. Thu V.T.H. 2018. A study on the mixed corrosion inhibitor with a dominant cathodic inhibitor for mild steel in aqueous chloride solution. J. Taiwan Inst. Chem. Eng. 91: 556-569.
  • Özkır D. Kayakırılmaz K. Bayol E. Gürten A.A. Kandemirli F. 2012. The inhibition effect of Azure A on mild steel in 1M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects. Corrosion Science. 56: 143–152.
  • Özkır D. Çifcibaşı Ö. 2017. The Investigation of the Adsorption of a Schiff Base Derivated from 2,5-Dichloroaniline as an Inhibitor on Mild Steel Corrosion in Acidic Medium by Electrochemical Methods. Engineering Sciences. 12:2, 97-107.
  • Özkır D. 2018. A new example of mild steel corrosion inhibitors synthesized from Chloroaniline: 2-[(2,5- dichlorophenylimino) methyl] phenol. OHU J. Eng. Sci. 7:2, 993-1003.
  • Özkır D. 2019a. A Newly Synthesized Schiff Base Derived from Condensation Reaction of 2,5-dichloroaniline and benzaldehyde: Its Applicability through Molecular Interaction on Mild Steel as an Acidic Corrosion Inhibitor by Using Electrochemical Techniques. J. Electrochem. Sci. Technol. 10:1, 37-54.
  • Özkır D. 2019b. The Electrochemical Variation of a Kind of Protein Staining and Food Dye as a New Corrosion Inhibitor on Mild Steel in Acidic Medium. International Journal of Electrochemistry. 2019: 1-11.
  • Özkır D. 2019c. A Corrosion Study: Use of Thionine dye having structurally metachromatic influence. Int. J. Chem. Technol. 3:1, 17-25.
  • Özkır D. Ezer T. 2020. A New Inhibitor Approach to the Corrosion of Mild Steel in Acidic Solution with Long-Term Impedance Tests: A New Application Area for Hypnum cupressiforme (Bryophyta). Anatolian Bryology. 6:2, 119-128.
  • Özkır D. Kayakırılmaz K. 2020. The Inhibitor Effect of (E)-5-[(4-(benzyl(methyl)amino)phenyl)diazenyl]-1,4-dimethyl-1H-1,2,4-triazol-4-ium zinc(II) Chloride, an Industrial Cationic Azo Dye, onto Reducing Acidic Corrosion Rate of Mild Steel. J. Electrochem. Sci. Technol. 11:3, 257-272.
  • Paton J.A. 1999. The Liverworts flora of the British Isles. Harley Press, 626 p. England.
  • Rodrigues F.A.d.S. Gonçalves Y.M.H. Horta B.A.C. Santos I.d.S. Silva B.V. D’Elia E. 2021. Experimental and theoretical studies of isonitrosoacetanilides derivatives as corrosion inhibitors for mild steel in 1 mol L−1 HCl. J. Mol. Struct. 1245: 131-256.
  • Salmasifar A. Edraki M. Alibakhshi E. Ramezanzadeh B. Bahlakeh G. 2021. Combined electrochemical/surface investigations and computer modeling of the aquatic Artichoke extract molecules corrosion inhibition properties on the mild steel surface immersed in the acidic medium. J. Mol. Liq. 327: 114856.
  • Smith A.J.E. 1996. The liverworts of Britain and Ireland, Cambridge University Press. 362 p. Cambridge.
  • Sürme Y. Gürten A.A. 2009. Role of polyethylene glycol tert-octylphenyl ether on corrosion behaviour of mild steel in acidic solution. Corros. Eng. Sci. Techn. 44:4, 304–311.
  • Tosun G. Yayli B. Özdemir T. Batan N. Bozdeveci A. Yayli N. 2015. Volatiles and Antimicrobial Activity of the Essential Oils of the Mosses Pseudoscleropodium purum, Eurhynchium striatum, and Eurhynchium angustirete Grown in Turkey. Rec. Nat. Prod. 9: 237-242.
  • Zhang X. Li W. Yu G. Zuo X. Luo W. Zhang J. Tan B. Fu A. Zhang S. 2020. Evaluation of Idesia polycarpa Maxim fruits extract as a natural green corrosion inhibitor for copper in 0.5 M sulfuric acid solution. J. Mol. Liq. 318: 114080.
  • Zohdy K.M. El-Sherif R.M. Ramkumar S. El-Shamy A.M. 2021. Quantum and electrochemical studies of the hydrogen evolution findings in corrosion reactions of mild steel in acidic medium. Upstream Oil and Gas Technology. 6: 100025.
There are 31 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Demet Özkır 0000-0002-8096-5755

Publication Date November 20, 2021
Submission Date August 19, 2021
Published in Issue Year 2021 Volume: 7 Issue: 2

Cite

APA Özkır, D. (2021). An Overview of Plagiochila porelloides (Marchantiophyta) as a New Environmentally Sustainable Green Corrosion Inhibitor for Mild Steel in Acidic Solution. Anatolian Bryology, 7(2), 119-130. https://doi.org/10.26672/anatolianbryology.984722

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